Recent advances in the synthesis of difluorinated architectures from trifluoromethyl groups

F Zhao, W Zhou, Z Zuo - Advanced Synthesis & Catalysis, 2022 - Wiley Online Library
Fluorine‐containing moieties are widely used in the pharmaceutical, agrochemical, and
material fields. Thus, these structures are of immense interest in the fields of organic …

Recent advance in the C–F bond functionalization of trifluoromethyl-containing compounds

G Yan, K Qiu, M Guo - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The C–F bond is the strongest single bond in organic compounds. It is the most challenging
task to study the activation of the C–F bond in organic synthesis. Trifluoromethyl-containing …

Chromium-catalyzed allylic defluorinative ketyl olefin coupling

C Zhang, Z Lin, Y Zhu, C Wang - Journal of the American …, 2021 - ACS Publications
Herein we report a chromium-catalyzed allylic defluorinative ketyl olefin coupling between
aldehydes and α-trifluoromethyl alkenes, which provides novel and efficient access to …

Transition-metal-catalyzed C–H allylation reactions

S Dutta, T Bhattacharya, DB Werz, D Maiti - Chem, 2021 - cell.com
Allylation reactions are one of the most fundamental and productive C− C bond-forming
transformations, as the allyl group can provide a useful handle for further manipulation …

Photocatalyzed Cascade Reactions of Cyclopropanols and α‐Trifluoromethyl‐Substituted Olefins for the Synthesis of Fused gem‐Difluorooxetanes

Y Zhang, Y Niu, Y Guo, J Wang, Y Zhang… - Angewandte …, 2022 - Wiley Online Library
Fluorinated fused rings are challenging to construct from simple starting materials. Herein,
we report the first photocatalyzed cascade reactions of readily available cyclopropanols and …

Metal-free, visible-light driven α-C (sp 3)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1, 3-enynes

ZH Yuan, H Xin, L Zhang, P Gao, X Yang, XH Duan… - Green …, 2023 - pubs.rsc.org
A metal free, visible-light driven α-C (sp3)–H gem-difluoroallylation of glycine derivatives
with trifluoromethyl alkenes and 1, 3-enynes is presented. This protocol features mild and …

α-Amino Acids and Peptides as Bifunctional Reagents: Carbocarboxylation of Activated Alkenes via Recycling CO2

LL Liao, GM Cao, YX Jiang, XH Jin, XL Hu… - Journal of the …, 2021 - ACS Publications
Carboxylic acids, including amino acids (AAs), have been widely used as reagents for
decarboxylative couplings. In contrast to previous decarboxylative couplings that release …

Visible‐Light‐Curable Acrylic Resins toward UV‐Light‐Blocking Adhesives for Foldable Displays

JH Back, Y Kwon, H Cho, H Lee, D Ahn… - Advanced …, 2023 - Wiley Online Library
Current technological advances in the organic light‐emitting diode panel design of foldable
smartphones demand advanced adhesives with UV‐blocking abilities, beyond their …

Recent advances in radical enabled selective C sp 3–F bond activation of multifluorinated compounds

S Li, W Shu - Chemical Communications, 2022 - pubs.rsc.org
Fluorine-containing molecules have found broad applications in pharmaceutical and
agrochemical industries as introducing fluorine into a molecule could significantly tune the …

Photocatalytic gem‐Difluoroolefination Reactions by a Formal C− C Coupling/Defluorination Reaction with Diazoacetates

F Li, C Pei, RM Koenigs - Angewandte Chemie International …, 2022 - Wiley Online Library
The photolysis of diazoalkanes to conduct singlet carbene transfer reactions of colored
diazoalkanes has recently attracted significant interest in organic synthesis. Herein, we …