Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Achieving selective C− H activation at a single and strategic site in the presence of multiple
C− H bonds can provide a powerful and generally useful retrosynthetic disconnection. In this …

Among sulfoximine derivatives containing a chiral sulfur center, benzothiadiazine‐1‐oxides
are important for applications in medicinal chemistry. Here, we report that the combination of …

Abstract (Pentamethylcyclopentadienyl) rhodium (RhCp*)‐catalyzed C H transformations
have emerged as a prosperous field in C H bond activation. Recent advances in this area …

Organic transformations that involve direct functionalization of C–H bonds represent an
attractive synthetic strategy that maximizes atom-and step-economy. With the generally high …

The functionalization of carbon–hydrogen bonds in non‐nucleophilic substrates using α‐
carbonyl sulfoxonium ylides has not been so far investigated, despite the potential safety …

Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated
coupling partners has been a valuable synthetic tool for the multiring molecular scaffolds …

The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

Rh (III)-catalyzed C–H activation assisted by an oxidizing directing group has evolved to a
mild and redox-economic strategy for the construction of heterocycles. Despite the success …

Chemodivergent and redox-neutral annulations between N-methoxybenzamides and
sulfoxonium ylides have been realized via Rh (III)-catalyzed C–H activation. The …