Multiplet effects in X-ray spectroscopy
F De Groot - Coordination Chemistry Reviews, 2005 - Elsevier
This review gives an overview of the presence of multiplet effects in X-ray spectroscopy, with
an emphasis on X-ray absorption studies on 3d transition metal ions in inorganic oxides and …
an emphasis on X-ray absorption studies on 3d transition metal ions in inorganic oxides and …
Open shells and multi-electron interactions: core level photoionization of the 3d metal atoms
This review covers the outer core level photoionization of the free 3d metal atoms from Sc to
Cu. The experimental 3p, 3s and 2p photoemission and photoabsorption spectra are …
Cu. The experimental 3p, 3s and 2p photoemission and photoabsorption spectra are …
Electron Spectroscopy Study of Li[Ni,Co,Mn]O2/Electrolyte Interface: Electronic Structure, Interface Composition, and Device Implications
G Cherkashinin, M Motzko, N Schulz… - Chemistry of …, 2015 - ACS Publications
In recent years, there have been significant efforts to understand the role of the electronic
structure of redox active materials according to their performance and thermodynamic …
structure of redox active materials according to their performance and thermodynamic …
Magnetic order in γ-Fe2O3 nanoparticles: a XMCD study
S Brice-Profeta, MA Arrio, E Tronc, N Menguy… - Journal of Magnetism …, 2005 - Elsevier
Spin-canting in spinel nanoparticles of maghemite has multiple origins, among which
surface effects, finite-size effects or chemical disorder effects. XMCD at the Fe L2, 3 edges …
surface effects, finite-size effects or chemical disorder effects. XMCD at the Fe L2, 3 edges …
L-edge X-ray absorption spectroscopy of non-heme iron sites: experimental determination of differential orbital covalency
EC Wasinger, FMF De Groot, B Hedman… - Journal of the …, 2003 - ACS Publications
X-ray absorption spectroscopy has been utilized to obtain the L-edge multiplet spectra for a
series of non-heme ferric and ferrous complexes. Using these data, a methodology for …
series of non-heme ferric and ferrous complexes. Using these data, a methodology for …
Identifying -electron symmetries of with O-edge resonant inelastic x-ray scattering
The recent discovery of spin-triplet superconductivity emerging from a nonmagnetic parent
state in UTe 2 has stimulated great interest in the underlying mechanism of Cooper pairing …
state in UTe 2 has stimulated great interest in the underlying mechanism of Cooper pairing …
Fluorescence yield detection: Why it does not measure the X-ray absorption cross section
FMF De Groot, MA Arrio, P Sainctavit, C Cartier… - Solid State …, 1994 - Elsevier
It is shown that fluorescence yield (FY) detection does not measure a pure X-ray absorption
spectrum if multiplet effects are important. The reason is that while the Auger decay is …
spectrum if multiplet effects are important. The reason is that while the Auger decay is …
Lifetime effect on the multiplet structure of 4d x-ray-photoemission spectra in heavy rare-earth elements
H Ogasawara, A Kotani, BT Thole - Physical Review B, 1994 - APS
X-ray-photoemission spectra of 4d (N 4, 5) core level in heavy rare-earth elements are
studied theoretically with the consideration of the 4d-4f4f (N 4, 5− N 6, 7 N 6, 7) super-Coster …
studied theoretically with the consideration of the 4d-4f4f (N 4, 5− N 6, 7 N 6, 7) super-Coster …
Spin-polarized x-ray emission of transition-metal ions: A comparison via and detection
X Wang, FMF de Groot, SP Cramer - Physical Review B, 1997 - APS
This paper demonstrates that spin-polarized x-ray-excitation spectra can be obtained using
K α emission as well as K β lines. A spin-polarized analysis of K α x-ray emission and the …
K α emission as well as K β lines. A spin-polarized analysis of K α x-ray emission and the …
Theory of X-ray photoemission and X-ray emission spectra in Mn compounds
M Taguchi, T Uozumi, A Kotani - Journal of the Physical Society of …, 1997 - journals.jps.jp
We analyze theoretically X-ray photoemission spectra (XPS) from Mn 2 p and 3 p core-levels
in Mn compounds and Mn Kβ X-ray emission spectra (XES) by means of an MX 6 cluster …
in Mn compounds and Mn Kβ X-ray emission spectra (XES) by means of an MX 6 cluster …