Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
Hydrogen atom transfer (HAT): a versatile strategy for substrate activation in photocatalyzed organic synthesis
The adoption of hydrogen atom transfer (HAT) in a photocatalytic approach, in which an
excited catalyst is responsible for substrate activation, offers unique opportunities in organic …
excited catalyst is responsible for substrate activation, offers unique opportunities in organic …
[图书][B] Visible light photocatalysis in organic chemistry
Filling the need for a ready reference that reflects the vast developments in this field, this
book presents everything from fundamentals, applications, various reaction types, and …
book presents everything from fundamentals, applications, various reaction types, and …
Photoorganocatalysis, small organic molecules and light in the service of organic synthesis: the awakening of a sleeping giant
Photocatalysis, the use of light to promote organic transformations, is a field of catalysis that
has received limited attention despite existing for over 100 years. With the revolution of …
has received limited attention despite existing for over 100 years. With the revolution of …
Accelerated and Scalable C(sp3)–H Amination via Decatungstate Photocatalysis Using a Flow Photoreactor Equipped with High-Intensity LEDs
Carbon–nitrogen bonds are ubiquitous in biologically active compounds, prompting
synthetic chemists to design various methodologies for their preparation. Arguably, the ideal …
synthetic chemists to design various methodologies for their preparation. Arguably, the ideal …
Photogenerated acyl/alkoxycarbonyl/carbamoyl radicals for sustainable synthesis
Acylation reactions are of crucial importance in synthesis since they provide access to
ketones or related derivatives. The well known acylations of aromatics (the Friedel–Crafts …
ketones or related derivatives. The well known acylations of aromatics (the Friedel–Crafts …
Decatungstate‐Mediated C(sp3)–H Heteroarylation via Radical‐Polar Crossover in Batch and Flow
Photocatalytic hydrogen atom transfer is a very powerful strategy for the regioselective C
(sp3)–H functionalization of organic molecules. Herein, we report on the unprecedented …
(sp3)–H functionalization of organic molecules. Herein, we report on the unprecedented …
[HTML][HTML] Photochemical oxidation of benzylic primary and secondary alcohols utilizing air as the oxidant
A mild and green photochemical protocol for the oxidation of alcohols to aldehydes and
ketones was developed. Utilizing thioxanthenone as the photocatalyst, molecular oxygen …
ketones was developed. Utilizing thioxanthenone as the photocatalyst, molecular oxygen …
[HTML][HTML] Photochemical metal-free aerobic oxidation of thiols to disulfides
N Spiliopoulou, CG Kokotos - Green Chemistry, 2021 - pubs.rsc.org
Thiol oxidation to disulfides is an area of great importance in organic synthesis, both for
synthetic and biological purposes. Herein, we report a mild, inexpensive and green …
synthetic and biological purposes. Herein, we report a mild, inexpensive and green …
Amide bond formation via aerobic photooxidative coupling of aldehydes with amines catalyzed by a riboflavin derivative
A Hassan Tolba, M Krupicka, J Chudoba… - Organic …, 2021 - ACS Publications
We report an effective, operationally simple, and environmentally friendly system for the
synthesis of tertiary amides by the oxidative coupling of aromatic or aliphatic aldehydes with …
synthesis of tertiary amides by the oxidative coupling of aromatic or aliphatic aldehydes with …