Gold-catalyzed heterocyclic syntheses through α-imino gold carbene complexes as intermediates
E Aguilar, J Santamaría - Organic Chemistry Frontiers, 2019 - pubs.rsc.org
Gold carbene complexes have been recognized as common intermediates in gold-catalyzed
organic syntheses. In this field, α-imino gold carbene complexes, in the last few years, have …
organic syntheses. In this field, α-imino gold carbene complexes, in the last few years, have …
[HTML][HTML] Extremely stable anthraquinone negolytes synthesized from common precursors
Synthetic cost and long-term stability remain two of the most challenging barriers for the
utilization of redox-active organic molecules in redox flow batteries for grid-scale energy …
utilization of redox-active organic molecules in redox flow batteries for grid-scale energy …
Gold-catalyzed hydrofluorination of electron-deficient alkynes: stereoselective synthesis of β-fluoro michael acceptors
TJ O'Connor, FD Toste - ACS catalysis, 2018 - ACS Publications
The gold (I)-catalyzed, stereoselective hydrofluorination of electron-deficient alkynes with
triethylamine trihydrogen fluoride (Et3N· 3HF) is described. Fluorinated α, β-unsaturated …
triethylamine trihydrogen fluoride (Et3N· 3HF) is described. Fluorinated α, β-unsaturated …
Ensembles of Metal Triflate Additives in Gold(I)-Catalyzed Formal [2 + 2 + 2] Cycloaddition of Carbonyls with Activated Terminal Alkynes: One-Pot Synthesis of 2H …
DB Sung, JS Lee - Organic Letters, 2023 - ACS Publications
Herein, we describe a gold (I)-catalyzed intermolecular formal [2+ 2+ 2] cycloaddition of a
carbonyl compound and a propiolate. A series of highly substituted 2 H-pyrans are accessed …
carbonyl compound and a propiolate. A series of highly substituted 2 H-pyrans are accessed …
Unraveling the anion/ligand interplay in the reaction mechanism of gold (I)-catalyzed alkoxylation of alkynes
In this work DFT calculations have been performed to investigate the anion/ligand interplay
in the reaction mechanism of alkoxylation of alkynes promoted by gold (I) catalysts of …
in the reaction mechanism of alkoxylation of alkynes promoted by gold (I) catalysts of …
Regioselective crossed aldol reactions under mild conditions via synergistic gold-iron catalysis
A synergistic gold-iron (Au-Fe) catalytic system was developed for sequential alkyne
hydration and vinyl Au addition to aldehydes or ketones. Fe (acac) 3 was identified as an …
hydration and vinyl Au addition to aldehydes or ketones. Fe (acac) 3 was identified as an …
Gold (I)‐Catalysed Asymmetric Hydroamination of Alkenes: A Silver‐and Solvent‐Dependent Enantiodivergent Reaction
MA Abadie, X Trivelli, F Medina, N Duhal… - … A European Journal, 2017 - Wiley Online Library
In the present study, we report the first silver‐dependent enantiodivergent gold‐catalysed
reaction. The asymmetric intramolecular hydroamination of alkenes catalysed by the …
reaction. The asymmetric intramolecular hydroamination of alkenes catalysed by the …
Gold catalyzed efficient preparation of dihydrobenzofuran from 1, 3-enyne and phenol
YJ Wang, Y Zhang, Z Qiang, JY Liang… - Chemical …, 2021 - pubs.rsc.org
A gold catalyzed formal intermolecular [2+ 3] cyclo-coupling of 1, 3-enynes with phenols was
developed to prepare dihydrobenzofuran derivatives with the addition of 2, 6 …
developed to prepare dihydrobenzofuran derivatives with the addition of 2, 6 …
Assessing the influence of phosphine substituents on the catalytic properties of self-stabilised digold (I) complexes with supporting ferrocene phosphinonitrile ligands
O Bárta, I Císařová, J Schulz, P Štěpnička - New Journal of Chemistry, 2019 - pubs.rsc.org
Gold (I) phosphine complexes are often used in catalysis, but the role of their auxiliary
ligands still remains poorly understood. Thus, building on our previous research, we …
ligands still remains poorly understood. Thus, building on our previous research, we …
Ligand effects in gold-carbonyl complexes: Evaluation of the bond dissociation energies using blackbody infrared radiative dissociation
D Gatineau, H Dossmann, H Clavier… - International Journal of …, 2021 - Elsevier
In a previous work, the ability of gold-carbonyl bond dissociation energies (BDEs) to
describe ligand effects in gold (I) complexes was probed using collision-induced …
describe ligand effects in gold (I) complexes was probed using collision-induced …