N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented …
The stabilization and isolation of highly reactive species has long been the subject of
chemical research. This review will focus on a large and important class of reactive species …
chemical research. This review will focus on a large and important class of reactive species …
Stable heavier carbene analogues
In recent decades, it has generally been recognized that carbenes play an important role as
transient intermediates. As a result of a number of stable carbenes having been isolated and …
transient intermediates. As a result of a number of stable carbenes having been isolated and …
The transition-metal chemistry of amidinatosilylenes,-germylenes and-stannylenes
L Álvarez-Rodríguez, JA Cabeza… - Coordination Chemistry …, 2015 - Elsevier
The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …
Bis (silylenyl)‐and Bis (germylenyl)‐Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon (II)–Cobalt Complexes
The chemistry of stable silylenes has received wide interest since the first isolation of N-
heterocyclic silylenes (NHSis) by Denk and West et al.[1] While stable silylenes have …
heterocyclic silylenes (NHSis) by Denk and West et al.[1] While stable silylenes have …
A systematic study of structure and E− H bond activation chemistry by sterically encumbered germylene complexes
M Usher, AV Protchenko, A Rit… - … A European Journal, 2016 - Wiley Online Library
A series of new germylene compounds has been synthesized offering systematic variation in
the σ‐and π‐capabilities of the α‐substituent and differing levels of reactivity towards E− H …
the σ‐and π‐capabilities of the α‐substituent and differing levels of reactivity towards E− H …
O, N-Heterocyclic germylenes as efficient catalysts for hydroboration and cyanosilylation of benzaldehyde
KV Arsenyeva, KI Pashanova, OY Trofimova… - New Journal of …, 2021 - pubs.rsc.org
New monomeric O, N-heterocyclic germylene AdAPGe (1) based on 4, 6-di-tert-butyl-N-
adamantyl-o-aminophenol is synthesized and structurally characterized. Germylene 1 in the …
adamantyl-o-aminophenol is synthesized and structurally characterized. Germylene 1 in the …
Mono‐and bidentate benzannulated N‐heterocyclic germylenes, stannylenes and plumbylenes
AV Zabula, FE Hahn - European Journal of Inorganic Chemistry, 2008 - Wiley Online Library
The current state of the chemistry of mono‐and bidentate N‐heterocyclic germylenes,
stannylenes, plumbylenes, and related compounds is reviewed with special emphasis …
stannylenes, plumbylenes, and related compounds is reviewed with special emphasis …
Isolation and Structure of Germylene‐Germyliumylidenes Stabilized by N‐Heterocyclic Imines
T Ochiai, T Szilvási, D Franz, E Irran… - Angewandte …, 2016 - Wiley Online Library
The ditopic germanium complex FGe (NIPr) 2Ge [BF4](3 [BF4]; IPr= 1, 3‐bis (2, 6‐
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
A Redox‐Switchable Germylene and its Ligating Properties in Selected Transition Metal Complexes
F Walz, E Moos, D Garnier, R Köppe… - … A European Journal, 2017 - Wiley Online Library
The synthesis, structure, and full characterization of a redox‐switchable germylene based on
a [3] ferrocenophane ligand arrangement,[Fc (NMes) 2Ge](4), is presented. The mesityl …
a [3] ferrocenophane ligand arrangement,[Fc (NMes) 2Ge](4), is presented. The mesityl …
Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp (CO) 2M Ge–C …
AC Filippou, KW Stumpf, O Chernov… - …, 2012 - ACS Publications
The reactions of the germylenoid Li (THF) 3GeCl2C (SiMe3) 3 with the carbonyl metalates Li
[CpMo (CO) 3] and K [CpW (CO) 3](Cp= η5-C5H5) in toluene afford selectively the …
[CpMo (CO) 3] and K [CpW (CO) 3](Cp= η5-C5H5) in toluene afford selectively the …