The direct introduction of diverse fluorinated motifs into feedstock molecules and advanced
intermediates is widely studied in pharmaceutical research and drug development. Among …

Radical vicinal carbohalofunctionalization of C–C multiple bonds via atom transfer
processes constitutes an efficient method for the construction of halogenated building blocks …

The sigma (σ)‐hole effect has emerged as a promising tool to construct novel architectures
endowed with new properties. A simple yet effective strategy for the generation of …

The photochemistry of organophosphorus compounds and their reactions with carbon‐
centred radicals was studied from the 1950s to the 70s, but has not been well exploited in …

In the last few years, many reagents and protocols have been developed to allow for the
efficient fluorofunctionalization of a diverse set of scaffolds ranging from alkanes, alkenes …

A visible-light-promoted fluoroalkylation-thiolation of alkenes is described. A 4-
tetrafluoropyridinylthio fragment serves as a photoredox-active group in the initiation step …

The incorporation of difluoromethylated (CF2) moiety into potentially useful parent
molecules lead to significant changes in metabolic stability, lipophilicity, and solubility of the …

Herein, we report a simple and versatile difluoromethylene-imide reaction in which a series
of olefins can undergo a difluoromethylenimine reaction under photocatalytic conditions …

An elegant tandem reaction process for transferring N-allyl amide into CF2H-β-amino
alcohol is described. This approach proceeded smoothly under visible light irradiation in the …

The rise of interest in using polycyclic aromatic hydrocarbons (PAHs) and molecular
graphenoids in optoelectronics has recently stimulated the growth of modern synthetic …