Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Recent advances in enzyme immobilization based on novel porous framework materials and its applications in biosensing

Y Feng, Y Xu, S Liu, D Wu, Z Su, G Chen, J Liu… - Coordination Chemistry …, 2022 - Elsevier
Enzyme immobilization in nano-space to maintain or even enhance their activity and stability
is generally challenging. In recent years, metal–organic frameworks (MOFs), covalent …

Copper-based metal–organic frameworks for biomedical applications

JE Cun, X Fan, Q Pan, W Gao, K Luo, B He… - Advances in Colloid and …, 2022 - Elsevier
Metal–organic frameworks (MOFs) are a class of important porous, crystalline materials
composed of metal ions (clusters) and organic ligands. Owing to the unique redox chemistry …

Metal–organic frameworks enhance biomimetic cascade catalysis for biosensing

W Xu, L Jiao, Y Wu, L Hu, W Gu, C Zhu - Advanced Materials, 2021 - Wiley Online Library
Multiple enzymes‐induced biological cascade catalysis guides efficient and selective
substrate transformations in vivo. The biomimetic cascade systems, as ingenious strategies …

Metal-organic frameworks (MOFs) and MOF composites based biosensors

B Mohanty, S Kumari, P Yadav, P Kanoo… - Coordination Chemistry …, 2024 - Elsevier
Metal-organic frameworks (MOFs) are novel hybrid materials that have shown unique
opportunities in biosensors. The well-defined geometry, porosity, structural tunability …

Enzyme mimics for engineered biomimetic cascade nanoreactors: mechanism, applications, and prospects

X Zhang, G Li, G Chen, D Wu, Y Wu… - Advanced Functional …, 2021 - Wiley Online Library
Multiple enzyme‐driven biological catalytic cascades occur in living organisms, guiding
highly efficient and selective transformations of substrates. Inspired by the merits of these …

Recent advances in emerging metal–and covalent–organic frameworks for enzyme encapsulation

C Wang, K Liao - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Enzyme catalysis enables complex biotransformation to be imitated. This biomimetic
approach allows for the application of enzymes in a variety of catalytic processes …

Hierarchical mesoporous metal–organic frameworks encapsulated enzymes: Progress and perspective

X Zhang, R Tu, Z Lu, J Peng, C Hou, Z Wang - Coordination Chemistry …, 2021 - Elsevier
Hierarchical mesoporous metal–organic frameworks (HM-MOFs) with adjustable mesopores
have shown great potential for the encapsulation of enzyme because of their enhanced …

MOF‐Hosted Enzymes for Continuous Flow Catalysis in Aqueous and Organic Solvents

R Greifenstein, T Ballweg, T Hashem… - Angewandte Chemie …, 2022 - Wiley Online Library
Fully exploiting the potential of enzymes in cell‐free biocatalysis requires stabilization of the
catalytically active proteins and their integration into efficient reactor systems. Although in …

Metal–organic framework-engineered enzyme/nanozyme composites: Preparation, functionality, and sensing mechanisms

Y Li, H Chai, Z Yuan, C Huang, S Wang, Y Sun… - Chemical Engineering …, 2024 - Elsevier
The utility of non-homogeneous nanomaterials for the immobilization of enzymes has been
demonstrated to enhance their catalytic performance. Alongside this, the advent of artificial …