Lanthanides and actinides in ionic liquids

K Binnemans - Chemical reviews, 2007 - ACS Publications
Ionic liquids are salts with a low melting point (below 100 C). 1-6 Several types of ionic
liquids are liquid at room temperature (room-temperature ionic liquids or RTILs). The cations …

Exploring actinide materials through synchrotron radiation techniques

WQ Shi, LY Yuan, CZ Wang, L Wang, L Mei… - Advanced …, 2014 - Wiley Online Library
Synchrotron radiation (SR) based techniques have been utilized with increasing frequency
in the past decade to explore the brilliant and challenging sciences of actinide‐based …

The vitality of uranium molecular chemistry at the dawn of the XXIst century

M Ephritikhine - Dalton Transactions, 2006 - pubs.rsc.org
The intent of this Dalton Perspective is to highlight the recent advances in uranium
molecular chemistry, with the results reported during the 2000–2006 period. This discipline …

Ionic liquids: new hopes for efficient lanthanide/actinide extraction and separation?

I Billard - Handbook on the physics and chemistry of rare earths, 2013 - Elsevier
Ionic Liquids are of great interest in all fields of chemistry and material science. Apart from
their “green” properties, their radioresistance and fantastic chemical versatility offer a new …

Speciation of uranyl complexes in ionic liquids by optical spectroscopy

P Nockemann, K Servaes, R Van Deun… - Inorganic …, 2007 - ACS Publications
Uranyl complexes dissolved in room-temperature ionic liquids have diagnostic absorption
and emission spectra which reflect the molecular symmetry and geometry. In particular, the …

The radiation chemistry of ionic liquids: a review

BJ Mincher, JF Wishart - Solvent Extraction and Ion Exchange, 2014 - Taylor & Francis
Ionic liquids have received increasing attention as media for radiochemical separations.
Recent literature includes examinations of the efficiencies and mechanisms of the solvent …

Insights into the Mechanism of Extraction of Uranium (VI) from Nitric Acid Solution into an Ionic Liquid by using Tri‐n‐butyl phosphate

DC Gaillard, M Boltoeva, I Billard, S Georg… - …, 2015 - Wiley Online Library
We present new results on the liquid–liquid extraction of uranium (VI) from a nitric acid
aqueous phase into a tri‐n‐butyl phosphate/1‐butyl‐3‐methylimidazolium bis …

Applications of functionalized ionic liquids

X Li, D Zhao, Z Fei, L Wang - Science in China Series B: Chemistry, 2006 - Springer
Recent developments of the synthesis and applications of functionalized ionic liquids
(including dual-functionalized ionic liquids) have been highlighted in this review. Ionic …

Uranyl Coordination in Ionic Liquids:  The Competition between Ionic Liquid Anions, Uranyl Counterions, and Cl- Anions Investigated by Extended X-ray Absorption …

C Gaillard, A Chaumont, I Billard, C Hennig… - Inorganic …, 2007 - ACS Publications
The first coordination sphere of the uranyl cation in room-temperature ionic liquids (ILs)
results from the competition between its initially bound counterions, the IL anions, and other …

Highly selective extraction of uranium from nitric acid medium with phosphine oxide functionalized pillar [5] arenes in room temperature ionic liquid

L Chen, Y Wang, X Yuan, Y Ren, N Liu, L Yuan… - Separation and …, 2018 - Elsevier
Three phosphine oxide functionalized pillar [5] arenes (POP5A) were evaluated for the
extraction of uranyl ion from nitric acid feed solutions in room temperature ionic liquid (RTIL) …