Covering: up to February 2011 The pyrrole-2-aminoimidazole (P-2-AI) alkaloids are a
growing family of marine alkaloids, now numbering well over 150 members, with high …

The preceding four decades have witnessed a major expansion in the field of free-radical
assisted reactions, as they are becoming a key tool in organic, polymer and complex natural …

A strategy that facilitates the construction of a wide variety of trisubstituted stereocenters
through a catalytically accessed common chiral intermediate could prove highly enabling for …

Covering: July 2010 to June 2012. Previous review: Nat. Prod. Rep., 2011, 28, 1143–1191.
Structurally diverse alkaloids containing five-membered heterocyclic subunits, such as …

Dimeric pyrrole–imidazole alkaloids represent a rich and topologically unique class of
marine natural products. This full account will follow the progression of efforts that …

Cycloaddition is an essential tool in chemical synthesis. Instead of using light or heat as a
driving force, marine sponges promote cycloaddition with a more versatile but poorly …

Biomimetic synthesis describes the field of organic chemistry that aims to emulate the
natural, biosynthetic processes toward natural products. As well as providing insight into …

We describe herein the assembly of the cis‐decalin framework through radical cyclization
initiated by metal‐catalyzed hydrogen atom transfer (MHAT), further applied it in the …

The development of a simple, efficient, scalable, and stereocontrolled synthesis of a
common intermediate en route to the axinellamines, massadines, and palau'amine is …

Hypervalent iodine (III) reagents have been vastly used in many useful organic
transformations. In this review article, we highlight the strategies that used the common …