Catalytic metal-based systems for controlled statistical copolymerisation of lactide with a lactone

E Stirling, Y Champouret, M Visseaux - Polymer Chemistry, 2018 - pubs.rsc.org
Polylactide (PLA) is currently considered as a major polymer which could serve as a
potential substitute to the widely used petroleum-based plastics. It is typically produced by …

Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands

J Burt, W Levason, G Reid - Coordination Chemistry Reviews, 2014 - Elsevier
Abstract Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-
dentate phosphine and arsine ligands (and including the very few examples of stibine and …

Simple and Efficient Zinc Catalysts for Synthesis and Chemical Degradation of Polyesters

F Santulli, D Pappalardo, M Lamberti… - ACS Sustainable …, 2023 - ACS Publications
A series of zinc complexes supported by tridentate imino-phenolate ligands with different
substituents on the phenolate ring and bearing a pyridyl ring as an additional coordinative …

Metal–ligand cooperation facilitates bond activation and catalytic hydrogenation with zinc pincer complexes

M Rauch, S Kar, A Kumar, L Avram… - Journal of the …, 2020 - ACS Publications
A series of PNP zinc pincer complexes capable of bond activation via aromatization/
dearomatization metal–ligand cooperation (MLC) were prepared and characterized …

Dinuclear Zinc–N‐Heterocyclic Carbene Complexes for Either the Controlled Ring‐Opening Polymerization of Lactide or the Controlled Degradation of Polylactide …

C Fliedel, D Vila‐Viçosa, MJ Calhorda… - …, 2014 - Wiley Online Library
We describe the synthesis of the new Zn–N‐heterocyclic carbene (NHC) alkoxide
complexes [(S, CNHC) ZnCl (OBn)] 2 (5) and [(O, CNHC) ZnCl (OBn)] 2 (6) for use as ring …

Use of cement kiln dust, blast furnace slag and marble sludge in the manufacture of sustainable artificial aggregates by means of cold bonding pelletization

F Colangelo, R Cioffi - Materials, 2013 - mdpi.com
In this work, three different samples of solid industrial wastes cement kiln dust (CKD),
granulated blast furnace slag and marble sludge were employed in a cold bonding …

Homoleptic phenoxy-imine pyridine zinc complexes: efficient catalysts for solvent free synthesis and chemical degradation of polyesters

S D'Aniello, S Laviéville, F Santulli, M Simon… - Catalysis Science & …, 2022 - pubs.rsc.org
The synthesis and structural characterization of six homoleptic zinc complexes supported by
monoanionic phenoxy-imine pyridine ligands bearing different substituents on the phenoxy …

Preparation and characterization of new geopolymer-epoxy resin hybrid mortars

F Colangelo, G Roviello, L Ricciotti, C Ferone, R Cioffi - Materials, 2013 - mdpi.com
The preparation and characterization of metakaolin-based geopolymer mortars containing
an organic epoxy resin are presented here for the first time. The specimens have been …

Zinc and magnesium catalysts for the synthesis for PLA and its degradation: Clues for catalyst design

F Santulli, G Gravina, M Lamberti, C Tedesco… - Molecular …, 2022 - Elsevier
Homoleptic and heteroleptic zinc and magnesium complexes bearing phenoxy-imine
pyridine ligands were synthetized and characterized. Several structural parameters such as …

Iso-Selective Ring-Opening Polymerization of rac-Lactide Catalyzed by Crown Ether Complexes of Sodium and Potassium Naphthalenolates

J Xiong, J Zhang, Y Sun, Z Dai, X Pan, J Wu - Inorganic chemistry, 2015 - ACS Publications
Two crown ether complexes of sodium and potassium naphthalenolates were synthesized
and entirely characterized. The two complexes can iso-selectively catalyze the ring-opening …