In this Review, we summarize the current state of the art in late‐transition‐metal‐catalyzed
reactions of acyl fluorides, covering both their synthesis and further transformations. In …

The activation of a carbon‐fluorine bond is one of the most challenging topics in modern
synthetic organic chemistry due to their low reactivity compared to other carbon‐halogen …

This Article describes the development of a base-free, nickel-catalyzed decarbonylative
coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate …

Cooperative bimetallic catalysis is a fundamental approach in modern synthetic chemistry.
We report bimetallic cooperative catalysis for the direct decarbonylative heteroarylation of …

This Article describes the development of a decarbonylative Pd-catalyzed aryl–fluoroalkyl
bond-forming reaction that couples fluoroalkylcarboxylic acid-derived electrophiles [RFC (O) …

Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …

Acyl fluorides are versatile reagents in organic synthesis. However, there is no precedent to
employ acyl fluorides as acyl radical precursors. We herein report an N-heterocyclic …

3, 3-Difluoro-1, 2-diphenylcyclopropene (CpFluor), a bench-stable fluorination reagent, has
been developed in the deoxyfluorination of carboxylic acids to afford various acyl fluorides …

Carboxylic acid derivatives containing acyl halides, anhydrides, esters, amides and acyl
nitriles are highly appealing electrophiles in transition‐metal‐catalyzed carbon‐carbon bond …

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been
developed to afford various arylsilanes with high efficiency and good functional-group …