Acyl Fluorides in Late‐Transition‐Metal Catalysis
Y Ogiwara, N Sakai - Angewandte Chemie International Edition, 2020 - Wiley Online Library
In this Review, we summarize the current state of the art in late‐transition‐metal‐catalyzed
reactions of acyl fluorides, covering both their synthesis and further transformations. In …
reactions of acyl fluorides, covering both their synthesis and further transformations. In …
Recent Advances in Transition‐metal‐catalyzed C−C Bond Formation via C(sp2)−F Bond Cleavage
L Fu, Q Chen, Y Nishihara - The Chemical Record, 2021 - Wiley Online Library
The activation of a carbon‐fluorine bond is one of the most challenging topics in modern
synthetic organic chemistry due to their low reactivity compared to other carbon‐halogen …
synthetic organic chemistry due to their low reactivity compared to other carbon‐halogen …
Mechanism and scope of nickel-catalyzed decarbonylative borylation of carboxylic acid fluorides
CA Malapit, JR Bour, SR Laursen… - Journal of the American …, 2019 - ACS Publications
This Article describes the development of a base-free, nickel-catalyzed decarbonylative
coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate …
coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate …
Bimetallic Cooperative Catalysis for Decarbonylative Heteroarylation of Carboxylic Acids via C‐O/C‐H Coupling
Cooperative bimetallic catalysis is a fundamental approach in modern synthetic chemistry.
We report bimetallic cooperative catalysis for the direct decarbonylative heteroarylation of …
We report bimetallic cooperative catalysis for the direct decarbonylative heteroarylation of …
Decarbonylative fluoroalkylation at palladium (II): from fundamental organometallic studies to catalysis
N Lalloo, CA Malapit, SM Taimoory… - Journal of the …, 2021 - ACS Publications
This Article describes the development of a decarbonylative Pd-catalyzed aryl–fluoroalkyl
bond-forming reaction that couples fluoroalkylcarboxylic acid-derived electrophiles [RFC (O) …
bond-forming reaction that couples fluoroalkylcarboxylic acid-derived electrophiles [RFC (O) …
Carbamoyl fluoride-enabled enantioselective Ni-catalyzed carbocarbamoylation of unactivated alkenes
Y Li, FP Zhang, RH Wang, SL Qi… - Journal of the American …, 2020 - ACS Publications
Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …
Photoinduced N-Heterocyclic Nitrenium-Catalyzed Single Electron Reduction of Acyl Fluorides for Phenanthridine Synthesis
L Bao, ZX Wang, XY Chen - Organic Letters, 2023 - ACS Publications
Acyl fluorides are versatile reagents in organic synthesis. However, there is no precedent to
employ acyl fluorides as acyl radical precursors. We herein report an N-heterocyclic …
employ acyl fluorides as acyl radical precursors. We herein report an N-heterocyclic …
Deoxyfluorination of carboxylic acids with CpFluor: access to acyl fluorides and amides
X Wang, F Wang, F Huang, C Ni, J Hu - Organic Letters, 2021 - ACS Publications
3, 3-Difluoro-1, 2-diphenylcyclopropene (CpFluor), a bench-stable fluorination reagent, has
been developed in the deoxyfluorination of carboxylic acids to afford various acyl fluorides …
been developed in the deoxyfluorination of carboxylic acids to afford various acyl fluorides …
Nickel or palladium‐catalyzed decarbonylative transformations of carboxylic acid derivatives
Z Wang, X Wang, Y Nishihara - Chemistry–An Asian Journal, 2020 - Wiley Online Library
Carboxylic acid derivatives containing acyl halides, anhydrides, esters, amides and acyl
nitriles are highly appealing electrophiles in transition‐metal‐catalyzed carbon‐carbon bond …
nitriles are highly appealing electrophiles in transition‐metal‐catalyzed carbon‐carbon bond …
Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides
X Wang, Z Wang, Y Nishihara - Chemical Communications, 2019 - pubs.rsc.org
Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been
developed to afford various arylsilanes with high efficiency and good functional-group …
developed to afford various arylsilanes with high efficiency and good functional-group …