Non-covalent interactions between metal cations and molecular hydrogen: spectroscopic studies of M+–H2 complexes

V Dryza, EJ Bieske - International Reviews in Physical Chemistry, 2013 - Taylor & Francis
We describe recent infrared spectroscopic investigations of charged complexes consisting of
a hydrogen or deuterium molecule attached to an atomic metal cation, including complexes …

Attaching molecular hydrogen to metal cations: perspectives from gas-phase infrared spectroscopy

V Dryza, BLJ Poad, EJ Bieske - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
In this perspective article we describe recent infrared spectroscopic investigations of mass-
selected M+–H2 and M+–D2 complexes in the gas-phase, with targets that include Li+–H2 …

Cerium Cation (Ce+) Reactions with H2, D2, and HD: CeH+ Bond Energy and Mechanistic Insights from Guided Ion Beam and Theoretical Studies

M Ghiassee, PB Armentrout - The Journal of Physical Chemistry A, 2020 - ACS Publications
Reactions of the atomic lanthanide cerium cation (Ce+) with H2, D2, and HD were studied
by using guided ion beam tandem mass spectrometry. Analysis of the kinetic-energy …

Infrared Spectroscopy of the Ag+−H2 Complex: Exploring the Connection Between Vibrational Band-Shifts and Binding Energies

V Dryza, EJ Bieske - The Journal of Physical Chemistry Letters, 2011 - ACS Publications
Storage of molecular hydrogen in solid media often depends on the interaction between
metal cations and H2. Under these circumstances, the strength of the interaction can …

Interactions between metal cations with H2 in the M+- H2 complexes: Performance of DFT and DFT-D methods

S Pakhira, T Debnath, K Sen, AK Das - Journal of Chemical Sciences, 2016 - Springer
The interactions between metal cations (Ni+, Cu+, Zn+) and H 2 molecule have been
investigated in detail using dispersion-corrected and-uncorrected double hybrid density …

[HTML][HTML] Praseodymium cation (Pr+) reactions with H2, D2, and HD: PrH+ bond energy and mechanistic insights from guided ion beam and theoretical studies

M Ghiassee, J Ewigleben… - The Journal of Chemical …, 2020 - pubs.aip.org
Guided ion beam tandem mass spectrometry was used to study the reactions of the atomic
lanthanide praseodymium cation (Pr+) with H 2, D 2, and HD as a function of collision …

Potential energy surface and rovibrational calculations for the Mg +–H2 and Mg +–D2 complexes

V Dryza, EJ Bieske, AA Buchachenko… - The Journal of Chemical …, 2011 - pubs.aip.org
Potential energy surface and rovibrational calculations for the |${\rm Mg}^+$| Mg +–|${\rm H}_2$|H2
and |${\rm Mg}^+$| Mg +–|${\rm D}_2$|D2 complexes | The Journal of Chemical Physics | AIP …

Activation of D2 by Neodymium Cation (Nd+): Bond Energy of NdH+ and Mechanistic Insights through Experimental and Theoretical Studies

M Ghiassee, PB Armentrout - The Journal of Physical Chemistry A, 2021 - ACS Publications
The kinetic-energy-dependent cross section for the reaction of Nd+ with D2 was studied by
using a guided ion beam tandem mass spectrometer. The formation of NdD+ is endothermic …

[HTML][HTML] Samarium cation (Sm+) reactions with H2, D2, and HD: SmH+ bond energy and mechanistic insights from guided ion beam and theoretical studies

M Demireva, PB Armentrout - The Journal of chemical physics, 2018 - pubs.aip.org
Guided ion beam tandem mass spectrometry is used to study the reaction of the lanthanide
samarium cation (Sm+) with H 2 and its isotopologues (HD and D 2) as a function of collision …

Activation of H2 by Gadolinium Cation (Gd+): Bond Energy of GdH+ and Mechanistic Insights from Guided Ion Beam and Theoretical Studies

M Demireva, PB Armentrout - The Journal of Physical Chemistry A, 2018 - ACS Publications
The energy-dependent reactions of the lanthanide gadolinium cation (Gd+) with H2, D2, and
HD are investigated using guided ion beam tandem mass spectrometry. From analysis of the …