Hydrogen bonding is an important interaction playing a key role in chemical, physical, and
biochemical processes. 1-4 One can mention numerous examples such as the role of …

Among many various kinds of molecular interactions, the H-bond has a special position. The
term is ubiquitous in the world that surrounds us, but also it is often applied in different ways …

A new type of hydrogen bond, called a dihydrogen bond, has recently been introduced. In
this bond a hydrogen is donated to another (hydridic) hydrogen. We apply a set of criteria …

Hydrogen bonding occupies a prominent position in modern chemistry. 1 It is fundamental
for molecular recognition and supramolecular synthesis and holds a central role in biology …

This article highlights recent efforts of this laboratory in the stabilization of highly reactive,
low-oxidation-state, main-group molecules using bulky N-heterocyclic carbene ligands [L …

The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …

This Account describes a new type of intermolecular interaction, the H ‚‚‚H or dihydrogen
bond, which operates between a conventional hydrogen bond donor such as an NH or OH …

Different measures of H-bond strength based on X− H proton donating bond properties and
on parameters of H⊙⊙⊙ Y distance (Y− proton acceptor within X− H⊙⊙⊙ YH bridges) are …

A new bifunctional pincer ligand framework bearing pendent proton-responsive hydroxyl
groups was prepared and metalated with Ru (II) and subsequently isolated in four discrete …

The dihydrogen-bonded complexes of methane and its fluoro and chloro derivatives with
lithium hydride are analyzed using ab initio methods as well as the Bader theory. All …