Metal–organic framework glass composites

R Lin, M Chai, Y Zhou, V Chen, TD Bennett… - Chemical Society …, 2023 - pubs.rsc.org
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2024 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …

Fabrication of amorphous metal-organic framework in deep eutectic solvent for boosted organophosphorus pesticide adsorption

Y Yin, C Fan, Y Shan, L Cheng - Journal of Environmental Chemical …, 2023 - Elsevier
Herein, we describe a new and sustainable strategy of directly constructing the amorphous
metal-organic framework (MOF) through the use of deep eutectic solvent (DES) for the highly …

Spectral and Temporal Manipulation of Ultralong Phosphorescence Based on Melt‐Quenched Glassy Metal–Organic Complexes for Multi‐Mode Photonic Functions

Y Gong, H Zhang, P Li, Y Bai, B Yin… - Advanced Functional …, 2024 - Wiley Online Library
Transparent glasses are ideal and robust hosts for a range of emission centers, while the
simultaneous manipulation of the temporal and spectral characteristics of emission remains …

The pressure response of Jahn–Teller-distorted Prussian blue analogues

HLB Boström, AB Cairns, M Chen, D Daisenberger… - Chemical …, 2024 - pubs.rsc.org
Jahn–Teller (JT) distorted CuII-containing compounds often display interesting structural
and functional behaviour upon compression. We use high-pressure X-ray and neutron …

Adsorption of perfluoroalkyl substances on deep eutectic solvent-based amorphous metal-organic framework: Structure and mechanism

Y Yin, C Fan, L Cheng, Y Shan - Environmental Research, 2024 - Elsevier
Perfluoroalkyl substances (PFASs) are a class of emerging organic pollutants characterized
by high toxicity, environmental persistence, and widespread detection in water sources. The …

Heterogeneity in enzyme/metal–organic framework composites for CO 2 transformation reactions

Y Shu, W Liang, J Huang - Green Chemistry, 2023 - pubs.rsc.org
Enzymatic reactions represent a promising alternative to chemical catalysis, including
chemical, photochemical, and electrochemical processes, for the conversion of CO2 into …

Melt-quenched carboxylate metal–organic framework glasses

M Kim, HS Lee, DH Seo, SJ Cho, E Jeon… - Nature …, 2024 - nature.com
Although carboxylate-based frameworks are commonly used architectures in metal-organic
frameworks (MOFs), liquid/glass MOFs have thus far mainly been obtained from azole-or …

Multiple Structural and Phase Transformations of MOF and Selective Hydrocarbon Gas Separation in its Amorphous, Glass Phase States

J Li, JX Wu, T Liu, J Yang, ML Wei… - Angewandte Chemie …, 2024 - Wiley Online Library
The first wide‐view image of multiple structural and phase transformations for MOFs, ranging
from crystal state transformations to the extreme limit approaching liquid/glass phase, was …

Meltable Aluminum Molecular Rings with Fluorescence and Nonlinear Optical Properties

ST Wang, WH Fang, J Zhang - Angewandte Chemie, 2024 - Wiley Online Library
Crystal–liquid–glass, which combines the tunable properties of crystalline compounds with
the processability of glasses, has emerged as a new class of materials for fabricating bulk …