The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed,
followed by the catalysts and mechanisms involved. Special emphasis is put on the common …

Stoichiometric and catalytic transition-metal reactions have attracted great interest for their
many applications in industrial and synthetic processes. Transition-metal reactions are …

There is considerable interest in both catalysts for CO2 conversion and understanding how
CO2 reacts with transition metal complexes. Here we develop a simple model for predicting …

The similarities and differences between the behavior of carbon-bound and terminal metal-
bound halogens and halide ions as potential hydrogen bond acceptors has been …

Hydrogen bonding occupies a prominent position in modern chemistry. 1 It is fundamental
for molecular recognition and supramolecular synthesis and holds a central role in biology …

The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …

Among the most common ligands found on transition metal catalysts are halide ions. Of the
commercially available catalysts or pre‐catalysts, most are halo–metal complexes. In recent …

The two-volume Encyclopedia of Supramolecular Chemistry offers authoritative, centralized
information on a rapidly expanding interdisciplinary field. User-friendly and high-quality …

Halogen bonding (XB) has been recently exploited as a significant tool for engineering
crystals involving coordination and organometallic compounds as tectons. This review, in …

A new homogeneous iridium catalyst gives hydrogenation of quinolines under
unprecedentedly mild conditions as low as 1 atm of H2 and 25° C. We report air-and …