Icosahedral boranes, carboranes, and metallacarboranes are extraordinarily robust
compounds with desirable properties such as thermal and redox stability, chemical …

Polyhedral boranes and carborane clusters are characterized by delocalized electron
deficient bonding, meaning that there are too few valence electrons for bonding to be …

Unlocking the full potential of rechargeable magnesium batteries has been partially
hindered by the reliance on chloride‐based complex systems. Despite the high anodic …

Realization of practical sodium metal batteries (SMBs) is hindered due to lack of compatible
electrolyte components, dendrite propagation, and poor understanding of anodic …

Designing solid electrolytes for all-solid-state-batteries that can withstand the extreme
electrochemical conditions in contact with an alkali metal anode and a high-voltage cathode …

Since the discoveries of boranes and carborane clusters,[1] relentless effort has been made
to understand their electronic structures,[2] particularly those of carborane compounds …

A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed
intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …

Abstract o‐Carborane‐based donor–acceptor dyads comprising an o‐carboranyl phenyl
unit combined with N‐carbazole (1) or 4‐phenyl‐N‐carbazole (2) were prepared, and their …

This work demonstrates the first successful electrochemical cycling of a redox-active boron
cluster-based material in the solid state. Specifically, we designed and synthesized an ether …

The regioselective derivatization of the monocarba-closo-dodecaborate anion via catalytic B–
H bond activation is reported. Amide directing groups in combination with rhodium and …