The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …

Metal phosphonate chemistry has witnessed a rapid development during the past two
decades. Numerous compounds have been synthesized which show new architectures and …

Sequential reaction of LH3 (LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) with Co
(OAc) 2· 4H2O followed by reaction with lanthanide salts afforded trinuclear heterobimetalllic …

Molecular amino-phosphonate cobalt –lanthanide clusters - Chemical Communications (RSC
Publishing) DOI:10.1039/C3CC40907D Royal Society of Chemistry View PDF VersionPrevious …

The coordination of methanol and ethanol molecules was observed in the construction of
three 1D coordination polymers composed of anti− anti carboxylato-bridged MnIII3O (Brppz) …

The use of phosphonic acids in the synthesis of mixed-metal CeMn complexes has led to the
formation of two phosphonate complexes with unusual topologies:[Ce2Mn6O6 (OH) 5 (t …

Five new isomorphic three-dimensional (3D) heterometallic 3d− 3d azide
complexes,[CuNi1− x Co x (N3) 2 (isonic) 2]∞(x= 0 for 1, x= 0.3 for 2, x= 0.5 for 3, x= 0.6 for …

We report a “modular synthesis approach” to multinuclear heterometallic oxo clusters in
lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM …

Reactions of 2-(1-Imidazole)-1-hydroxyl-1, 1′-ethylidenediphosphonic acid (ImhedpH4)
and cobalt or manganese salts under hydrothermal conditions result in three new metal …

We report the synthesis, structures, and magnetic properties of twelve iron (III) phosphonate
cages:[Fe4 (μ3-O) Cl (PhCO2) 3 (PhPO3) 3 (py) 5] 1,[Fe4 (μ3-O)(tBuCO2) 4 (C10H17PO3) 3 …