N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

Polymerization of polar monomers mediated by main-group Lewis acid–base pairs

M Hong, J Chen, EYX Chen - Chemical reviews, 2018 - ACS Publications
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

M Fèvre, J Pinaud, Y Gnanou, J Vignolle… - Chemical Society …, 2013 - pubs.rsc.org
The chemistry of N-heterocyclic carbenes (NHCs) has witnessed tremendous development
in the past two decades: NHCs have not only become versatile ligands for transition metals …

Organocatalysis: opportunities and challenges for polymer synthesis

MK Kiesewetter, EJ Shin, JL Hedrick… - …, 2010 - ACS Publications
Organocatalysis offers a number of opportunities in polymer synthesis and was among the
earliest methods of catalyzing the synthesis of polyesters. In the following Perspective we …

Lewis pair polymerization: perspective on a ten-year journey

ML McGraw, EYX Chen - Macromolecules, 2020 - ACS Publications
Ten years have passed since the conception of what was termed Lewis pair polymerization
(LPP) that employs Lewis acid and base in pairs to not only activate monomers but also …

Coordination polymerization of polar vinyl monomers by single-site metal catalysts

EYX Chen - Chemical reviews, 2009 - ACS Publications
1.1 Background A prolific coupling of polymer science with organometallic chemistry has
recently yielded phenomenal scientific and commercial successes in the production of …

Polyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization

AL Brocas, C Mantzaridis, D Tunc, S Carlotti - Progress in Polymer Science, 2013 - Elsevier
Epoxide derivatives constitute a broad family of monomers which are able to be polymerized
by anionic or related nucleophilic ring-opening mechanism. The main synthetic strategies …

Alane‐Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High …

Y Zhang, GM Miyake, EYX Chen - Angewandte Chemie, 2010 - infona.pl
Außergewöhnlich aktiv sind Al (C 6 F 5) 3‐basierte klassische und frustrierte Lewis‐Paare
mit ausgewählen Phosphanen oder N‐heterocyclischen Carbenen in der Polymerisation …

Opportunities for organocatalysis in polymer synthesis via step-growth methods

A Bossion, KV Heifferon, L Meabe, N Zivic… - Progress in Polymer …, 2019 - Elsevier
Organocatalysis has emerged as an invaluable tool for polymer synthesis and has already
demonstrated versatility for replacing organometallic catalysts in many polymerization …

Macromolecular architectures through organocatalysis

S Hu, J Zhao, G Zhang, H Schlaad - Progress in Polymer Science, 2017 - Elsevier
In virtue of the rising demand for metal-free polymeric materials, organocatalytic
polymerization has emerged and blossomed unprecedentedly in the past 15 years into an …