Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Structure–reactivity–property relationships in covalent adaptable networks

V Zhang, B Kang, JV Accardo… - Journal of the American …, 2022 - ACS Publications
Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …

[HTML][HTML] Wound microenvironment self-adaptive hydrogel with efficient angiogenesis for promoting diabetic wound healing

Z Shao, T Yin, J Jiang, Y He, T Xiang, S Zhou - Bioactive Materials, 2023 - Elsevier
Neovascularization is critical to improve the diabetic microenvironment, deliver abundant
nutrients to the wound and promote wound closure. However, the excess of oxidative stress …

Recent progress in self-healing polymers and hydrogels based on reversible dynamic B–O bonds: boronic/boronate esters, borax, and benzoxaborole

S Cho, SY Hwang, DX Oh, J Park - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Intrinsic self-healing polymeric materials are substances that relieve external stress and
restore their original mechanical properties after extreme damage via dynamic covalent …

Toward stimuli‐responsive dynamic thermosets through continuous development and improvements in covalent adaptable networks (CANs)

M Podgórski, BD Fairbanks, BE Kirkpatrick… - Advanced …, 2020 - Wiley Online Library
Covalent adaptable networks (CANs), unlike typical thermosets or other covalently
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …

Reactive metal boride nanoparticles trap lipopolysaccharide and peptidoglycan for bacteria-infected wound healing

Y Meng, L Chen, Y Chen, J Shi, Z Zhang… - Nature …, 2022 - nature.com
Bacteria and excessive inflammation are two main factors causing non-healing wounds.
However, current studies have mainly focused on the inhibition of bacteria survival for …

The Rise of Boron-Containing Compounds: Advancements in Synthesis, Medicinal Chemistry, and Emerging Pharmacology

RJ Grams, WL Santos, IR Scorei, A Abad-García… - Chemical …, 2024 - ACS Publications
Boron-containing compounds (BCC) have emerged as important pharmacophores. To date,
five BCC drugs (including boronic acids and boroles) have been approved by the FDA for …

Dynamic bonds: adaptable timescales for responsive materials

SV Wanasinghe, OJ Dodo… - Angewandte Chemie, 2022 - Wiley Online Library
Dynamic bonds introduce unique properties such as self‐healing, recyclability, shape
memory, and malleability to polymers. Significant efforts have been made to synthesize a …

Physical and chemical factors influencing the printability of hydrogel-based extrusion bioinks

SC Lee, G Gillispie, P Prim, SJ Lee - Chemical reviews, 2020 - ACS Publications
Bioprinting researchers agree that “printability” is a key characteristic for bioink
development, but neither the meaning of the term nor the best way to experimentally …

Engineering hydrogel adhesion for biomedical applications via chemical design of the junction

G Bovone, OY Dudaryeva, B Marco-Dufort… - ACS Biomaterials …, 2021 - ACS Publications
Hydrogel adhesion inherently relies on engineering the contact surface at soft and hydrated
interfaces. Upon contact, adhesion normally occurs through the formation of chemical or …