Enantioselective and enantiospecific transition-metal-catalyzed cross-coupling reactions of organometallic reagents to construct C–C bonds

AH Cherney, NT Kadunce, SE Reisman - Chemical Reviews, 2015 - ACS Publications
The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …

Chemodivergent reactions

IP Beletskaya, C Nájera, M Yus - Chemical Society Reviews, 2020 - pubs.rsc.org
An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …

Copper-catalyzed borylative difunctionalization of π-systems

A Whyte, A Torelli, B Mirabi, A Zhang, M Lautens - ACS Catalysis, 2020 - ACS Publications
Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Diastereodivergent desymmetric annulation to access spirooxindoles: chemical probes for mitosis

YH Wen, F Yang, S Li, X Yao, J Song… - Journal of the American …, 2023 - ACS Publications
Spirooxindoles have emerged as promising architectures for engineering biologically active
compounds. The diastereodivergent construction of unique scaffolds of this type with full …

Iron-catalyzed reactions in organic synthesis

C Bolm, J Legros, J Le Paih, L Zani - Chemical reviews, 2004 - ACS Publications
Metal complexes are essential instruments in the toolbox of organic chemists. The current
requirements for clean, fast, efficient, and selective processes have increased the demand …

Coordination− insertion copolymerization of fundamental polar monomers

A Nakamura, S Ito, K Nozaki - Chemical reviews, 2009 - ACS Publications
Akifumi Nakamura (left) was born in 1984 in Kanagawa, Japan. He received his BS degree
in 2007 and MS degree in 2009 from the University of Tokyo under the guidance of …

Rhodium-catalyzed asymmetric 1, 4-addition and its related asymmetric reactions

T Hayashi, K Yamasaki - Chemical Reviews, 2003 - ACS Publications
It has been well-documented that catalytic asymmetric synthesis is a field of great
importance in its practical usefulness as well as its scientific interest. 1 Among several types …

Chiral diphosphine and monodentate phosphorus ligands on a spiro scaffold for transition-metal-catalyzed asymmetric reactions

JH Xie, QL Zhou - Accounts of chemical research, 2008 - ACS Publications
The preparation of chiral compounds in enantiomerically pure form is a challenging goal in
modern organic synthesis. The use of chiral metal complex catalysis is a powerful …

Recent applications of chiral ferrocene ligands in asymmetric catalysis

R Gómez Arrayás, J Adrio… - Angewandte Chemie …, 2006 - Wiley Online Library
Despite the impressive progress achieved in asymmetric catalysis during the last decade, an
increasing number of new catalysts, ligands, and applications are reported every year to …

Chiral sulfur ligands for asymmetric catalysis

M Mellah, A Voituriez, E Schulz - Chemical reviews, 2007 - ACS Publications
The preparation of new enantiopure ligands that provide a chiral environment to metals so
that they perform efficient asymmetric catalysis is one of the most straightforward challenges …