Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …

Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

Catalytic alkene difunctionalization via Si− H and C− H activations represents an ideal atom‐
and step‐economic pathway for quick assembly of molecular complexity. We herein …

An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-
azido alcohols has been developed. The aerobic oxidative generation of azido radical …

The selective radical/radical cross‐coupling of two different organic radicals is a great
challenge due to the inherent activity of radicals. In this paper, a copper‐catalyzed …

An unprecedented and challenging radical–radical cross‐coupling of α‐aminoalkyl radicals
with monofluoroalkenyl radicals derived from gem‐difluoroalkenes was achieved. This first …

Functionalization of alkenes has been well investigated by chemists, thus it has been
extensively applied in organic synthesis and industries. In the past few decades, transition …

This review focuses on the intramolecular cyclization of molecules through C–O, C–N and C–
S bonds forming C–H functionalizations with an emphasis on the literature after 2000 …

A zerovalent copper-and cobalt-catalyzed direct coupling of the sp3 α-carbon of alcohols
with alkenes and hydroperoxides was developed in which the hydroperoxides acted as …