Carbenes are important intermediates in organic chemistry and have been widely applied in
various types of organic reactions, ranging from cycloaddition reactions and sigmatropic …

Photochemistry has recently attracted the interest of synthetic chemists to conduct photolysis
reactions of diazoalkanes. In this feature article, we provide a concise overview on this field …

The development of new sustainable reactions and protocols is essential to fulfill the
growing demands of every branch of organic chemistry for greener synthetic methodologies …

Considering the recent rapid advancement of synthetic technologies promoted by visible
light in the last 15 years, the use of photocatalysts has been rightfully justified based on the …

A metal-free and unprecedented strategy has been established for the construction of S-
alkyl phosphorothioates through visible-light-driven four-component reactions of α …

A green and sustainable oxime ether formation method via the visible-light-promoted O–H
functionalization of oximes with diazo esters is described. The reaction occurs under very …

We developed an efficient visible-light-mediated formal carbene insertion reaction of 1, 3-
diketones with diazoesters for the construction of enantioenriched 1, 4-dicarbonyl …

Among the available methods to increase the molecular complexity, sigmatropic
rearrangements occupy a distinct position in organic synthesis. Despite being known for …

The reaction mechanism of oxygen and sulfur ylide mediated rearrangements is even today
a matter of debate. In this report, we describe ring expansion reactions of oxetane and …

An efficient and environmentally friendly method for the synthesis of organic carbamates
from carbon dioxide has been developed via photolysis of α-aryldiazoesters under mild …