Imaging the dynamics of gas phase reactions

MNR Ashfold, NH Nahler, AJ Orr-Ewing… - Physical Chemistry …, 2006 - pubs.rsc.org
Ion imaging methods are making ever greater impact on studies of gas phase molecular
reaction dynamics. This article traces the evolution of the technique, highlights some of the …

Experimental detection of tetraoxygen

F Cacace, G De Petris, A Troiani - … Chemie International Edition, 2001 - Wiley Online Library
[9] A. Fürstner, K. Radkowski, Chem. Commun. 2001, 671±672, and references therein.[10]
a) A. Fürstner, Angew. Chem. 2000, 112, 3140±3172; Angew. Chem. Int. Ed. 2000, 39 …

Oxalyl chloride a clean source of chlorine atoms for kinetic studies

AV Baklanov, LN Krasnoperov - The Journal of Physical Chemistry …, 2001 - ACS Publications
Oxalyl chloride,(COCl) 2, has been characterized as a photolytic source of chlorine atoms for
kinetic studies. UV absorption spectrum of oxalyl chloride, as well as the photodissociation …

Gas-and particle-phase products from the chlorine-initiated oxidation of polycyclic aromatic hydrocarbons

M Riva, RM Healy, PM Flaud, E Perraudin… - The Journal of …, 2015 - ACS Publications
The chlorine atom (Cl)-initiated oxidation of three polycyclic aromatic hydrocarbons (PAHs;
namely, naphthalene, acenaphthylene, and acenaphthene) was investigated. Experiments …

Kinetics of the aC 3 H 5+ O 2 reaction, investigated by photoionization using synchrotron radiation

D Schleier, P Constantinidis, N Faßheber… - Physical Chemistry …, 2018 - pubs.rsc.org
The kinetics of the combustion-relevant reaction of the allyl radical, a-C3H5, with molecular
oxygen has been studied in a flow tube reactor at the vacuum ultraviolet (VUV) beamline of …

Vacuum Ultraviolet Photoionization of C3

C Nicolas, J Shu, DS Peterka, M Hochlaf… - Journal of the …, 2006 - ACS Publications
Photoionization efficiency (PIE) curves for C3 molecules produced by laser ablation are
measured from 11.0 to 13.5 eV with tunable vacuum ultraviolet undulator radiation. A step in …

Kinetics and products of the self-reaction of propargyl radicals

EV Shafir, IR Slagle, VD Knyazev - The Journal of Physical …, 2003 - ACS Publications
The kinetics and product branching of the self-reaction of propargyl radicals, C3H3+ C3H3→
products (1), have been studied as functions of temperature. Rate constants of reaction 1 …

Imaging the molecular channel in acetaldehyde photodissociation: roaming and transition state mechanisms

L Rubio-Lago, GA Amaral, A Arregui… - Physical Chemistry …, 2012 - pubs.rsc.org
The roaming dynamics in the photodissociation of acetaldehyde is studied through the first
absorption band, in the wavelength interval ranging from 230 nm to 325 nm. Using a …

Experimental determination of the rate constant of the reaction between C2H5O2 and OH radicals

EP Faragó, C Schoemaecker, B Viskolcz… - Chemical Physics …, 2015 - Elsevier
The rate constant of the reaction C 2 H 5 O 2+ OH→ Products has been measured at T= 296
K using laser photolysis coupled to CRDS and LIF. C 2 H 5 O 2 was generated from the …

A crossed molecular beam investigation of the reaction Cl+ propane→ HCl+ C3H7 using VUV synchrotron radiation as a product probe

DA Blank, N Hemmi, AG Suits, YT Lee - Chemical physics, 1998 - Elsevier
We have used the crossed molecular beam technique to study the hydrogen atom
abstraction from propane by atomic chlorine over a wide range of collision energies. The …