N-Heterocyclic carbenes and their precursors in functionalised porous materials

Y Wang, JP Chang, R Xu, S Bai, D Wang… - Chemical Society …, 2021 - pubs.rsc.org
Though N-heterocyclic carbenes (NHCs) have emerged as diverse and powerful discrete
functional molecules in pharmaceutics, nanotechnology, and catalysis over decades, the …

Recent advances in the catalytic N-methylation and N-trideuteromethylation reactions using methanol and deuterated methanol

V Goyal, N Sarki, A Narani, G Naik, K Natte… - Coordination Chemistry …, 2023 - Elsevier
N-methylamine functionalities are valuable motifs, which play vital roles in the properties
and activities of essential fine and bulk chemicals including molecules used in life science …

Multi-Functionality of Methanol in Sustainable Catalysis: Beyond Methanol Economy

G Sivakumar, R Kumar, V Yadav, V Gupta… - ACS …, 2023 - ACS Publications
Methanol is a fundamental feedstock and is widely used in the chemical and petroleum
industries. It can serve as a C1 source to make a variety of C–C and C–N bond formation …

Selective transformation of vicinal glycols to α-hydroxy acetates in water via a dehydrogenation and oxidization relay process by a self-supported single-site iridium …

L Shen, ZN Chen, Q Zheng, J Wu, X Xu, T Tu - ACS Catalysis, 2021 - ACS Publications
α-Hydroxy acids have attracted broad attention because of their prevalence in bioactive
molecules and biodegradable polymers, but their conventional syntheses are usually …

Simple RuCl3‐catalyzed N‐Methylation of Amines and Transfer Hydrogenation of Nitroarenes using Methanol

N Sarki, V Goyal, NK Tyagi, Puttaswamy… - …, 2021 - Wiley Online Library
Methanol is a potential hydrogen source and C1 synthon, which finds interesting
applications in both chemical synthesis and energy technologies. The effective utilization of …

Acceptorless dehydrogenation of primary alcohols to carboxylic acids by self-supported NHC-Ru single-site catalysts

S Yin, Q Zheng, J Chen, T Tu - Journal of Catalysis, 2022 - Elsevier
The acceptorless dehydrogenation of diverse aromatic and aliphatic primary alcohols to
corresponding carboxylic acids has been accomplished by self-supported NHC-Ru single …

Autotandem Catalyst: From Acylhydrazones to N′,N′-Methylaliphatic Acylhydrazides via Transfer Hydrogenation/N-Methylation with Methanol Catalyzed by a Cp …

S Luo, X Xu, P Zhang, Q Shi, X Yang, F Li - Organic Letters, 2022 - ACS Publications
A new strategy for the synthesis of N′, N′-methylaliphatic acylhydrazides from
acylhydrazones via transfer hydrogenation/N-methylation with methanol as both the …

Manganese‐Catalyzed Mono‐N‐Methylation of Aliphatic Primary Amines without the Requirement of External High‐Hydrogen Pressure

J Ji, Y Huo, Z Dai, Z Chen, T Tu - Angewandte Chemie, 2024 - Wiley Online Library
The synthesis of mono‐N‐methylated aliphatic primary amines has traditionally been
challenging, requiring noble metal catalysts and high‐pressure H2 for achieving satisfactory …

From hydrogen autotransfer process to deuterium autotransfer process: The N-trideuteromethylation of amines with deuterated methanol to trideuteromethylated …

P Liu, X Chen, X Xu, L Yang, G Zeng, C Ye, Q Shi… - Journal of …, 2022 - Elsevier
A Cp* Ir complex bearing a flexible and functional 6, 6′-(OH) 2-2, 2′-dipyridylamine ligand
was designed, synthesized and found to be a general and efficient catalyst for the synthesis …

Sustainable and Affordable Synthesis of (Deuterated) N-Methyl/Ethyl Amines from Nitroarenes

A Mondal, A Karattil Suresh, G Sivakumar… - Organic …, 2022 - ACS Publications
The sustainable and affordable synthesis of (deuterated) N-methyl/ethyl amines directly from
nitroarenes is disclosed. The reaction is catalyzed by a single-site manganese catalyst and …