Synthesis, structure, and bonding in polyiodide and metal iodide− iodine systems
PH Svensson, L Kloo - Chemical Reviews, 2003 - ACS Publications
Iodine was discovered in 1811 by the French chemist Curtois during the process of
manufacturing potassium nitrate, with which he supplied the Napoleon armies. 1 While …
manufacturing potassium nitrate, with which he supplied the Napoleon armies. 1 While …
Words in supramolecular chemistry: the ineffable advances of polyiodide chemistry
M Savastano - Dalton Transactions, 2021 - pubs.rsc.org
Polyiodide chemistry has a rich history deeply intertwined with the development of
supramolecular chemistry. Technological and theoretical interest in polyiodides has not …
supramolecular chemistry. Technological and theoretical interest in polyiodides has not …
Iodine-redox-chemistry-modulated ion transport channels in MXene enables high energy storage capacity
J Wang, L Hao, J Qin, X Zhang, Y Cheng, L Yue… - Energy Storage …, 2024 - Elsevier
Abstract Ti 3 C 2 T x MXene anode often faces the great challenge of a low capacity due to
its sluggish ion transport kinetics. Herein we report iodine-redox-chemistry-modulated …
its sluggish ion transport kinetics. Herein we report iodine-redox-chemistry-modulated …
Ultrafast photodissociation of I3. Coherent photochemistry in solution
We report a comprehensive study of the UV photolysis of I3− in ethanol solution, using
femtosecond time resolved transient transmission experiments. We interpret our results to …
femtosecond time resolved transient transmission experiments. We interpret our results to …
Iodine speciation in deep eutectic solvents
JM Hartley, S Scott, Z Dilruba, AJ Lucio… - Physical Chemistry …, 2022 - pubs.rsc.org
Iodine has been shown to act as a good electrocatalyst for metal digestion in deep eutectic
solvents (DESs) but little is known about its speciation or reactivity in these high chloride …
solvents (DESs) but little is known about its speciation or reactivity in these high chloride …
Relativistically parameterized extended Hueckel calculations. 3. Structure and bonding for some compounds of uranium and other heavy elements
P Pyykkoe, LL Lohr Jr - Inorganic Chemistry, 1981 - ACS Publications
The relativistically parameterized extended Hiickel molecular orbital method REX is used to
explore the effects of relativity upon molecularorbital energies and compositions. The …
explore the effects of relativity upon molecularorbital energies and compositions. The …
Investigating the Structural Symmetrization of CsI3 at High Pressures through Combined X-ray Diffraction Experiments and Theoretical Analysis
T Porȩba, S Racioppi, G Garbarino… - Inorganic …, 2022 - ACS Publications
Structural evolution of cesium triiodide at high pressures has been revealed by synchrotron
single-crystal X-ray diffraction. Cesium triiodide undergoes a first-order phase transition …
single-crystal X-ray diffraction. Cesium triiodide undergoes a first-order phase transition …
Factors Controlling Asymmetrization of the Simplest Linear I3– and I42– Polyiodides with Implications for the Nature of Halogen Bonding
G Manca, A Ienco, C Mealli - Crystal growth & design, 2012 - ACS Publications
This paper investigates geometric and electronic features of linear I3–and I42–anions, as
building blocks of larger polyiodides. Most experimental structures are quasi D∞ h, although …
building blocks of larger polyiodides. Most experimental structures are quasi D∞ h, although …
Extensive theoretical investigation: influence of the electrostatic environment on the I3 −···I3 − anion–anion interaction
F Groenewald, C Esterhuysen, J Dillen - Theoretical Chemistry Accounts, 2012 - Springer
A theoretical study of the triiodide ion and I 3−··· I 3− interactions in the dimer was performed
using various levels of theory and basis sets. Optimisations in the gas phase and in an …
using various levels of theory and basis sets. Optimisations in the gas phase and in an …
Femtosecond Chemical Dynamics in Solution: Photodissociation of I3‐
We report a study of the UV photolysis of I3− in alcohol solutions, using femtosecond time‐
resolved transient transmission experiments. We interpret our results to indicate that …
resolved transient transmission experiments. We interpret our results to indicate that …