Self-assembled nanoreactors

DM Vriezema, M Comellas Aragonès… - Chemical …, 2005 - ACS Publications
In nature, chemical conversions take place in a confined environment and are closely
geared to each other such that the product of one reaction is the substrate or catalyst of the …

Peptide-and protein-based hydrogels

AM Jonker, DWPM Löwik… - Chemistry of …, 2012 - ACS Publications
Hydrogels are polymeric networks, capable of absorbing large amounts of water and
biological fluids. They are insoluble due to the presence of chemical or physical cross-links …

High activity and efficient turnover by a simple, self-assembled “artificial Diels–Alderase”

V Martí-Centelles, AL Lawrence… - Journal of the American …, 2018 - ACS Publications
The Diels–Alder (DA) reaction is a cornerstone of synthesis, yet Nature does not use
catalysts for intermolecular [4+ 2] cycloadditions. Attempts to create artificial “Diels …

Reaction solvent selection: the potential of water as a solvent for organic transformations

HC Hailes - Organic process research & development, 2007 - ACS Publications
The increasing need for more sustainable strategies in organic synthesis has led to a
growing interest in the use of water and other nonclassical solvents. This short review …

Epoxide-opening cascades promoted by water

I Vilotijevic, TF Jamison - Science, 2007 - science.org
Selectivity rules in organic chemistry have been inferred largely from nonaqueous
environments. In contrast, enzymes operate in water, and the chemical effect of the medium …

Effects of the hydrophobicity of the reactants on Diels− Alder reactions in water

A Meijer, S Otto, JBFN Engberts - The Journal of Organic …, 1998 - ACS Publications
To assess the importance of the hydrophobicity of different parts of diene and dienophile on
the aqueous acceleration of Diels− Alder reactions, second-order rate constants have been …

Diels-Alder reactions in water. effects of hydrophobicity and hydrogen bonding

S Otto, W Blokzijl, JBFN Engberts - The Journal of Organic …, 1994 - ACS Publications
In orderto check whether the activated complex for the Diels-Alder reactions of 5-substituted
1, 4-naphthoquinones la-e with cyclopentadiene (2) is more polar in water than in other …

Reversible Diels− Alder reactions for the generation of dynamic combinatorial libraries

PJ Boul, P Reutenauer, JM Lehn - Organic letters, 2005 - ACS Publications
Condensation reactions between various dienes and dienophiles have been screened for
reversibility. Functionalized fulvenes, bearing in particular biological groups, and …

Clean synthesis of 1, 8-dioxo-octahydroxanthene derivatives catalyzed by p-dodecylbenezenesulfonic acid in aqueous media

TS Jin, JS Zhang, JC Xiao, AQ Wang, TS Li - Synlett, 2004 - thieme-connect.com
An efficient and convenient approach to the synthesis of 3, 3, 6, 6-tetramethyl-9-aryl-1, 8-
dioxo-octahydroxanthene derivatives using p-dodecylbenezenesulfonic acid (DBSA) as the …

Green synthesis of tetrahydrobenzo [b] pyrans, pyrano [2, 3-c] pyrazoles and spiro [indoline-3, 4′-pyrano [2, 3-c] pyrazoles catalyzed by nano-structured diphosphate …

B Maleki, N Nasiri, R Tayebee, A Khojastehnezhad… - RSC …, 2016 - pubs.rsc.org
A green and recoverable nano-structured diphosphate (Na2CaP2O7) was synthesized and
fully characterized using FT-IR spectra, X-ray diffraction patterns (XRD), scanning electron …