Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds

A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Efficient iodine uptake of ultra thermally stable conjugated copolymers bearing biaceanthrylenyl moieties and contorted aromatic units using a [3+ 2] palladium …

N Baig, S Shetty, R Bargakshatriya, SK Pramanik… - ACS …, 2023 - ACS Publications
A novel series of copolymers made from alternating aromatic surrogates with contorted and
spiro compounds, denoted as BCP1–3, was successfully synthesized employing a …

The design, synthesis and application of rubicene based polycyclic aromatic hydrocarbons (PAHs)

L Ma, Y Han, Q Shi, H Huang - Journal of Materials Chemistry C, 2023 - pubs.rsc.org
Rubicene, a key nanofragment of C70, is attracting great attention owing to its unique
molecular structure and physicochemical properties. As an indeno-annelated polycyclic …

Synthesis and Photophysical Properties of Soluble N‐Doped Rubicenes via Ruthenium‐Catalyzed Transfer Hydrogenative Benzannulation

WG Shuler, SP Parvathaneni… - … A European Journal, 2021 - Wiley Online Library
Ruthenium‐catalyzed butadiene‐mediated benzannulation enabled the first synthesis of 3,
10‐(di‐tert‐butyl) rubicene and its N‐doped derivatives as well as preliminary studies on …

Electron Acceptors Based on Cyclopentannulated Anthanthrenes

Y Du, HB Lovell, F Lirette, JF Morin… - The Journal of Organic …, 2021 - ACS Publications
We demonstrate the preparation of anthanthrene derivatives with fused five-membered
rings. These new derivatives are prepared by a palladium catalyzed cyclopentannulation …

Post-Functionalization of End-Capping Twistacenes with Pyrene Units

J Xiao, S Wang, T Ye - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
The size, shape, edge structure of nanographenes can significantly affect their physical
properties. Meanwhile, the introduction of pentagon, heptagon, octagon into the parent …

Quadrupolar Cyclopenta[hi]aceanthrylene‐Based Electron Donor‐Acceptor‐Donor Conjugates: Charge Transfer versus Charge Separation

C Schierl, W Alex, LM Mateo, B Ballesteros… - Angewandte …, 2019 - Wiley Online Library
Abstract Cyclopenta [hi] aceanthrylenes (CPAs) have been functionalized at two of the
peripheral positions with electronically inert trimethylsilylethynyl (1), as well as with electron …

Donor‐acceptor copolymers from cyclopentannulation polymerizations with dicyclopenta [cd, jk] pyrene and dicyclopenta [cd, lm] perylene acceptors

A Uddin, KN Plunkett - Journal of Polymer Science, 2020 - Wiley Online Library
A series of donor‐acceptor copolymers with dicyclopenta [cd, jk] pyrene and dicyclopenta
[cd, lm] perylene acceptor units was prepared via palladium catalyzed cyclopenta …

Synthesis of anthradithiophene containing conjugated polymers via a cross-coupling strategy

WA Hussain, KN Plunkett - RSC advances, 2021 - pubs.rsc.org
New conjugated polymers that incorporate dihexylanthradithiophene (DHADT) in the main
chain were prepared by Stille, Sonogashira, and Yamamoto cross-coupling polymerization …