Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2024 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …

Glass and liquid chemistry of coordination polymers and MOFs

S Horike - Bulletin of the Chemical Society of Japan, 2023 - academic.oup.com
The chemistry of coordination polymers and metal-organic frameworks (MOFs) has
progressed largely with the development of crystallography. The study of “disordered …

Synthesizing Interpenetrated Triazine‐based Covalent Organic Frameworks from CO2

S Zhang, L Lombardo, M Tsujimoto… - Angewandte Chemie …, 2023 - Wiley Online Library
Crystalline triazine‐based covalent organic frameworks (COFs) are aromatic nitrogen‐rich
porous materials. COFs typically show high thermal/chemical stability, and are promising for …

Dual‐Proton Conductor for Fuel Cells with Flexible Operational Temperature

W Li, W Liu, W Jia, J Zhang, Q Zhang… - Advanced …, 2024 - Wiley Online Library
The properties of proton conductors determine the operating temperature range of fuel cells.
Typically, phosphoric acid (PA) proton conductors exhibit excellent proton conductivity …

Photoexcited anhydrous proton conductivity in coordination polymer glass

N Ma, S Impeng, S Bureekaew… - Journal of the …, 2023 - ACS Publications
Optically switchable proton-conductive materials will enable the development of artificial
ionic circuits. However, most switchable platforms rely on conformational changes in crystals …

Ion transport and conduction in metal–organic framework glasses

M Chai, R Chen, K Xu, Y Chen, S Ma, R Lin… - Journal of Materials …, 2023 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a group of highly tunable porous materials composed
of metal nodes and organic linkers. Although MOF research has predominantly focused on …

Heterogenous CO2 Reduction Photocatalysis of Transparent Coordination Polymer Glass Membranes Containing Metalloporphyrins

H Izu, H Tabe, Y Namiki, H Yamada… - Inorganic Chemistry, 2023 - ACS Publications
Transparent and grain boundary-free substrates are essential to immobilize molecular
photocatalysts for efficient photoirradiation reactions without unexpected light scattering and …

Melt-quenched carboxylate metal–organic framework glasses

M Kim, HS Lee, DH Seo, SJ Cho, E Jeon… - Nature …, 2024 - nature.com
Although carboxylate-based frameworks are commonly used architectures in metal-organic
frameworks (MOFs), liquid/glass MOFs have thus far mainly been obtained from azole-or …

Smoke in the MOF liquid

C Das, S Henke - Nature Materials, 2023 - nature.com
Smoke in the MOF liquid | Nature Materials Skip to main content Thank you for visiting
nature.com. You are using a browser version with limited support for CSS. To obtain the best …

Ionization of a neutral MOF to disperse and anchor acid for boosting anhydrous proton conductivity

K Wang, L Si, Y Tian, F Yang - Microporous and Mesoporous Materials, 2024 - Elsevier
Although incorporation of proton conducting molecules (PCMs) is one of the most effective
methods to enhance the anhydrous conductivity, most materials including MOFs are …