The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

An efficient geometrical E→ Z isomerisation of alkenyl silanes is disclosed via selective
energy transfer using an inexpensive organic sensitiser. Characterised by operational …

As main-group chemistry, in particular boron chemistry, has expanded and developed over
the past 20 years, one reagent has risen to prominence as well. Tris (pentafluorophenyl) …

The synthesis of a range of brominated-Bn-containing (n= 1, 2) polycyclic aromatic
hydrocarbons (PAHs) is achieved simply by reacting BBr3 with appropriately substituted …

Hydrosilylation of borylalkynes to borylsilylalkenes (with a different arrangement of
substituents) has been successfully developed. The cis-addition of SiH group to the CC …

Organoboron compounds now known as versatile building blocks are broadly used in a
variety of transformations in the field of organic synthesis, drug synthesis, and material …

The synthesis of organoboron compounds have attracted the attention of the synthetic
community. In particular, molecules with C (sp2)‐B bonds enable the transformation to new …

Abstract The Mes2P‐C≡ C‐SiMe3 alkyne reacts with the borane H2B‐Fmes by means of a
rare 1, 1‐hydroboration reaction to give an unsaturated C2‐bridged frustrated P/B‐H Lewis …

Transfer C–H borylation is an isodesmic approach to the borylation reaction using B–C-
containing molecules as boron sources. In this work, we report that 2-mercaptothiazole and …

The addition of phosphinoboronate ester Ph2PBpin (pin= 1, 2‐O2C2Me4)(1) to a number of
different N‐heterocycles has been investigated. Reaction of 1 with pyridine resulted in highly …