The elusive hydrogen-bonded sulfur monoxide–hydroxyl radical complex (• OH··· OS), a
missing intermediate in the atmospheric chemistry of SO2, was generated in the 266 nm …

Perfectly controlled molecules are at the forefront of the quest to explore chemical reactivity
at ultra low temperatures. Here, we investigate for the first time the formation of the long-lived …

Context The rationalization of acid rain formation steps is fundamental for mitigating its
effects. It is believed the hydroxysulfinyl radical is an intermediate species for the production …

The reaction H+ SO2→ OH+ SO is important in the combustion and atmospheric chemistry,
as well as the interstellar medium. It also represents a typical complex-forming reaction with …

An analytical global potential energy surface for the ground electronic state of SSiH is here
reported. The function is based upon ab initio energies calculated at Davidson-corrected …

Complexes formed in reactive collisions highlight the nature of intramolecular interactions.
The present work reports a detailed quasi-classical trajectory study of the reaction OH (vi …

High translational temperatures appear in the air inside the shock waves layers created by
relatively large meteorites, reentry space vehicles, and hypersonic missiles. Under these …

The present work reported a full-dimension quasi-classical trajectory study of the activation
and deactivation processes in the collisions of N 2 and H 2, when one of the molecules is …

We have studied the vibrational relaxation of excited α‐chlorotoluene and dissociations of
C Hring and C Cl bonds of α‐chlorotoluene in the α‐chlorotoluene+ H2/D2 collision at …

Rate coefficients of bi-molecular chemical reactions are fundamental for kinetic models. The
rate coefficient dependence on temperature is commonly extracted from the analyses of the …