Abstract Palladium‐catalysed Suzuki–Miyaura cross‐couplings of organoboronic acids or
organotrifluoroborates with aryl and alkenyl halides or triflates have become classic …

The (site-selective) derivatization of amino acids and peptides represents an attractive field
with potential applications in the establishment of structure–activity relationships and …

Non‐proteogenic amino acids and functionalized peptides are important motifs in modern
drug discovery. Here we report that AlaB can serve as universal building blocks in the …

Palladium-catalyzed cross-coupling reactions have been investigated in multicatalytic
processes to synthesize disubstituted alkenes and alkanes from carbonyl derivatives. The …

A photochemical protocol using blue light allows the N–H insertion of amides, isatins,
sulfonamides and imides into aryldiazoacetates to afford the corresponding α-amino esters …

Homochiral, highly functionalised organolithium reagents derived from l-serine have been
generated and reacted with electrophiles. The novel enantiomerically pure adducts thus …

Selective modifications of peptides and proteins have emerged as a promising strategy to
develop novel mechanistic probes and prepare compounds with translational potentials …

The stereoselective synthesis of a new amino acid phosphonium salt was described by
quaternization of melting triphenylphosphine with the γ-iodo NHBoc-amino ester, derived …

Over the past decade, major advances in the preparation and utilization of organoboron
reagents have been applied to virtually all areas of organic synthesis. The present review …

A review with 1663 references to transition-metal catalyzed or mediated reactions and
functional group preparations.