Electrochemical late-stage functionalization
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …
diversification of novel molecular entities with improved physicochemical or biological …
Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
Photoelectrochemical asymmetric catalysis enables site-and enantioselective cyanation of benzylic C–H bonds
The enantioselective functionalization of ubiquitous C (sp 3)–H bonds is ideally suited for
the construction of three-dimensional chiral structures. However, organic molecules often …
the construction of three-dimensional chiral structures. However, organic molecules often …
Organic electrochemistry: molecular syntheses with potential
Efficient and selective molecular syntheses are paramount to inter alia biomolecular
chemistry and material sciences as well as for practitioners in chemical, agrochemical, and …
chemistry and material sciences as well as for practitioners in chemical, agrochemical, and …
Copper-catalyzed radical relay in C (sp 3)–H functionalization
Z Zhang, P Chen, G Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …
Radical C(sp3)–H functionalization and cross-coupling reactions
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …
Photoelectrochemical asymmetric catalysis enables direct and enantioselective decarboxylative cyanation
XL Lai, M Chen, Y Wang, J Song… - Journal of the American …, 2022 - ACS Publications
The development of efficient and sustainable methods for decarboxylative transformations is
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
Catalyzing electrosynthesis: a homogeneous electrocatalytic approach to reaction discovery
Conspectus Electrochemistry has been used as a tool to drive chemical reactions for over
two centuries. With the help of an electrode and a power source, chemists are bestowed with …
two centuries. With the help of an electrode and a power source, chemists are bestowed with …
A tutorial on asymmetric electrocatalysis
Electrochemistry has emerged as a powerful means to enable redox transformations in
modern chemical synthesis. This tutorial review delves into the unique advantages of …
modern chemical synthesis. This tutorial review delves into the unique advantages of …
The persistent radical effect in organic synthesis
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …
selective cross‐coupling of two different radicals is challenging and not a synthetically …