The chemistry of organic nitroso compounds (X-NdO) is in many ways linked to the
chemistry of nitric oxide (NO). In addition to reacting with metal compounds to form metal …

In order to produce various isocyanates, catalyzed carbonylations of nitroaromatic
compounds constitute a set of very appealing reactions for industry. These environmentally …

For many, the name“isocyanate” became unfortunately associated with the tragic evening of
December 2, 1984, where an accident in Union Carbide's Bhopal plant caused the death of …

The synthesis and application of three examples of a new class of chiral (C 2) atropisomeric
diphosphines characterized by two interconnected five-membered heteroaromatic rings …

Since its original discovery over a century ago, the water‐gas shift reaction (WGSR) has
played a crucial role in industrial chemistry, providing a source of H2 to feed fundamental …

Nitroalkenes have been called 'chemical chameleons' due to their versatility in numerous
synthetic transformations. Herein, we describe the first transition metal-catalyzed …

Studies on the coordination of nitrosoarene (ArNO) ligands to late-transition metals are used
to provide the first definition of the geometric, spectroscopic, and computational parameters …

A reaction is reported, resulting in the allylic amination of an unactivated olefin, cyclohexene,
by a nitroarene, catalyzed by Ru3 (CO) 12/Ar-BIAN (Ar-BIAN= bis (arylimino) …

The chemistry of C-nitroso-compounds commenced in 1874 with the synthesis of p-
nitrosodimethylaniline (NODMA) and of nitrosobenzene (NOB). It was not until the 1960s …

Kinetic and mechanistic studies on the deoxygenation of nitroarenes by Ru (dppe)(CO) 3,
where dppe= 1, 2-bis (diphenylphosphino) ethane, are described. The products of the …