CO2/13CO2 Dynamic Exchange in the Formate Complex [(2,9-(tBu)2-phen)Cu(O2CH)] and Its Catalytic Activity in the Dehydrogenation of Formic Acid
K Phung, P Thuéry, JC Berthet, T Cantat - Organometallics, 2023 - ACS Publications
Monometallic formate complexes of copper (I) are rare. We report here the synthesis,
characterization, and crystal structure of the simple tricoordinate [(phen*) CuI (κ1-O2CH)](1) …
characterization, and crystal structure of the simple tricoordinate [(phen*) CuI (κ1-O2CH)](1) …
A Gold (I)–Acetylene Complex Synthesised using Single‐Crystal Reactivity
CL Johnson, DJ Storm, MA Sajjad… - Angewandte …, 2024 - Wiley Online Library
Using single‐crystal to single‐crystal solid/gas reactivity the gold (I) acetylene complex [Au
(L1)(η2‐HC≡ CH)][BArF4] is cleanly synthesized by addition of acetylene gas to single …
(L1)(η2‐HC≡ CH)][BArF4] is cleanly synthesized by addition of acetylene gas to single …
Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO2 Hydrogenation
H Song, NK Szymczak - Angewandte Chemie, 2024 - Wiley Online Library
We present a series of borane‐tethered cyclic (alkyl)(amino) carbene (cAAC)‐copper
complexes, including a borane‐capped Cu (I) hydride. This hydride is unusually hydridic …
complexes, including a borane‐capped Cu (I) hydride. This hydride is unusually hydridic …
Mechanistic Investigation into Copper (I) Hydride Catalyzed Formic Acid Dehydrogenation
RLM Bienenmann, AO Loyo, M Lutz, DLJ Broere - ACS catalysis, 2024 - ACS Publications
Copper (I) hydride complexes are typically known to react with CO2 to form their
corresponding copper formate counterparts. However, recently it has been observed that …
corresponding copper formate counterparts. However, recently it has been observed that …
Insertion reactions and structural studies of [(NHC) CuH] 2 with nitrogen-based substrates
BL Tran, JD Erickson - Polyhedron, 2024 - Elsevier
The stoichiometric and catalytic reactions of Cu-H dimers supported by N-heterocyclic
carbenes (NHCs) have mainly focused on the insertions of aldehydes, ketones, CO 2, and …
carbenes (NHCs) have mainly focused on the insertions of aldehydes, ketones, CO 2, and …
Coinage Metal Effect on the Reduction of Carbon Dioxide with Monomeric Metal‐Hydride Complexes
D Sorbelli, L Belpassi… - European Journal of …, 2024 - Wiley Online Library
The role of the coinage metal in monomeric hydride complexes for the reduction of carbon
dioxide to formate has been computationally addressed in this work. The common reaction …
dioxide to formate has been computationally addressed in this work. The common reaction …
N-Heterocyclic Carbenes: Studies in Metallation, Ligand Modification, and Property Determination
MQ Lim - 2024 - search.proquest.com
Abstract N-Heterocyclic Carbenes (NHCs) have significantly impacted organometallic
chemistry as ligands in transition metal catalysis, offering strong electron-donating …
chemistry as ligands in transition metal catalysis, offering strong electron-donating …