Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry

MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …

Detection of two interstellar polycyclic aromatic hydrocarbons via spectral matched filtering

BA McGuire, RA Loomis, AM Burkhardt, KLK Lee… - Science, 2021 - science.org
Unidentified infrared emission bands are ubiquitous in many astronomical sources. These
bands are widely, if not unanimously, attributed to collective emissions from polycyclic …

Discovery of the pure polycyclic aromatic hydrocarbon indene (c-C9H8) with GOTHAM observations of TMC-1

AM Burkhardt, KLK Lee, PB Changala… - The Astrophysical …, 2021 - iopscience.iop.org
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar
and protostellar sources, but the unambiguous identification of any individual PAH has …

Synthetic approaches to complex organic molecules in the cold interstellar medium

E Herbst, RT Garrod - Frontiers in Astronomy and Space Sciences, 2022 - frontiersin.org
The observation and synthesis of organic molecules in interstellar space is one of the most
exciting and rapidly growing topics in astrochemistry. Spectroscopic observations especially …

Discovery of two isomers of ethynyl cyclopentadiene in TMC-1: Abundances of CCH and CN derivatives of hydrocarbon cycles

J Cernicharo, M Agúndez, RI Kaiser… - Astronomy & …, 2021 - aanda.org
We report the detection of two isomers of ethynyl cyclopentadiene (cC 5 H 5 CCH), namely 1-
and 2-ethynyl-1, 3-cyclopentadiene, in the direction of TMC-1. We derive column densities of …

Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1

KLK Lee, PB Changala, RA Loomis… - The Astrophysical …, 2021 - iopscience.iop.org
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …

An investigation of spectral line stacking techniques and application to the detection of HC11N

RA Loomis, AM Burkhardt, CN Shingledecker… - Nature …, 2021 - nature.com
As the inventory of interstellar molecules continues to grow, the gulf between small species,
whose individual rotational lines can be observed with radio telescopes, and large ones …

A Search for Heterocycles in GOTHAM Observations of TMC-1

TJ Barnum, MA Siebert, KLK Lee… - The Journal of …, 2022 - ACS Publications
We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …

Aromatic cycles are widespread in cold clouds

M Agúndez, N Marcelino, B Tercero… - Astronomy & …, 2023 - aanda.org
We report the detection of large hydrocarbon cycles toward several cold dense clouds. We
observed four sources (L1495B, Lupus-1A, L483, and L1527) in the Q band (31− 50 GHz) …

The UMIST database for astrochemistry 2022

TJ Millar, C Walsh, M Van de Sande… - Astronomy & …, 2024 - aanda.org
Context. Detailed astrochemical models are a key component to interpret the observations of
interstellar and circumstellar molecules since they allow important physical properties of the …