Thermal expansion in organic crystals

BK Saha - Journal of the Indian Institute of Science, 2017 - Springer
Though a large number of thermal expansion studies have been reported on inorganic
systems, a considerably large number on metal–organic-based systems, but those on purely …

Luminescent metal–organic frameworks with anthracene chromophores: small-molecule sensing and highly selective sensing for nitro explosives

X Li, L Yang, L Zhao, XL Wang, KZ Shao… - Crystal Growth & …, 2016 - ACS Publications
Five new luminescent metal–organic frameworks (MOFs),[Cd (bdc)(dia) 0.5 (MeOH)](DMA)
0.5 (1),[Cd2O (1, 4-ndc) 2 (dia) 2 (H2O)]· DMA (2),[Cd (1, 4-ndc)(dia)]· MeOH (3),[Cd …

Strong π-stacking causes unusually large anisotropic thermal expansion and thermochromism

M Dharmarwardana, BM Otten… - Proceedings of the …, 2021 - National Acad Sciences
π-stacking in ground-state dimers/trimers/tetramers of N-butoxyphenyl (naphthalene)
diimide (BNDI) exceeds 50 kcal⋅ mol− 1 in strength, drastically surpassing that for the* 3 …

A series of porous interpenetrating metal–organic frameworks based on fluorescent ligands for nitroaromatic explosive detection

XS Zeng, HL Xu, YC Xu, XQ Li, ZY Nie… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Four porous interpenetrating metal–organic frameworks (MOFs), namely,[Cd2 (Tipb) 2 (btc)
Cl]· Gx (1),[Cd (Tipb)(tdc)]· Gx (2),[Cd (Tipb)(fdc)]· Gx (3), and [Cd5 (Tipb) 4 (btc) 2Cl2 (DMF) …

((R)-(−)-3-Hydroxyquinuclidium)[FeCl 4]; a plastic hybrid compound with chirality, ferroelectricity and long range magnetic ordering

P González-Izquierdo, O Fabelo… - Journal of Materials …, 2021 - pubs.rsc.org
Quinuclidinium salts and their derivatives are now in the focus of materials science as
building units of multifunctional materials. Their properties can be easily switchable …

Insights into structure–property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides

YKJ Bejaoui, F Philippi, HG Stammler, K Radacki… - Chemical …, 2023 - pubs.rsc.org
Room temperature ionic liquids of cyclic sulfonimide anions ncPFSI (ring size: n= 4–6) with
the cations [EMIm]+(1-ethyl-3-methylimidazolium),[BMIm]+(1-butyl-3-methylimidazolium) …

Colossal positive and negative axial thermal expansion induced by scissor-like motion of a two-dimensional hydrogen bonded network in an organic salt

B Dwivedi, A Shrivastava, L Negi… - Crystal Growth & Design, 2019 - ACS Publications
A variable temperature single crystal X-ray diffraction study revealed an unusual thermal
expansion property of an organic salt, imidazolium 4-hydroxybenzene carboxylate, which …

Confined water in imidazolium based ionic liquids: a supramolecular guest@ host complex case

M Zanatta, AL Girard, G Marin, G Ebeling… - Physical Chemistry …, 2016 - pubs.rsc.org
It is well known that the macroscopic physico-chemical properties of ionic liquids (ILs) are
influenced by the presence of water that strongly interferes with the supramolecular …

Tunable ionic control of polymeric films for inkjet based 3D printing

E Karjalainen, DJ Wales… - ACS Sustainable …, 2018 - ACS Publications
Inkjet printing is a powerful additive manufacturing (AM) technique to generate advanced
and complex geometries. However, requirements of low viscosity and surface tension are …

Unusual Thermal Expansion in Hydrogen Bonded Network of an Organic Salt Induced by Large Transverse Vibration of Atoms

L Negi, S Kumar, B Dwivedi, D Das - Crystal Growth & Design, 2021 - ACS Publications
Thermal expansion of an organic salt, prepared by solvent-drop grinding of terephthalic acid
and imidazole in a 1: 2 ratio, has been studied over a wide range of temperature 100–430 K …