Cu (II) carboxylate arene C─ H functionalization: Tuning for nonradical pathways
We report carbon-hydrogen acetoxylation of nondirected arenes benzene and toluene, as
well as related functionalization with pivalate and 2-ethylhexanoate ester groups, using …
well as related functionalization with pivalate and 2-ethylhexanoate ester groups, using …
Ethylene dimerization and oligomerization using bis (phosphino) boryl supported Ni complexes
F Kong, P Ríos, C Hauck… - Journal of the …, 2022 - ACS Publications
We report the dimerization and oligomerization of ethylene using bis (phosphino) boryl
supported Ni (II) complexes as catalyst precursors. By using alkylaluminum (III) compounds …
supported Ni (II) complexes as catalyst precursors. By using alkylaluminum (III) compounds …
Mechanistic studies of styrene production from benzene and ethylene using [(η2-C2H4) 2Rh (μ-OAc)] 2 as catalyst precursor: Identification of a Bis-RhI Mono-CuII …
We report a combined experimental and computational study focused on the mechanism of
oxidative conversion of benzene and ethylene to styrene using [(η2-C2H4) 2Rh (μ-OAc)] 2 …
oxidative conversion of benzene and ethylene to styrene using [(η2-C2H4) 2Rh (μ-OAc)] 2 …
Functionalization of RhIII–Me Bonds: Use of “Capping Arene” Ligands to Facilitate Me–X Reductive Elimination
S Gu, J Chen, CB Musgrave III, ZM Gehman… - …, 2021 - ACS Publications
We show how to improve the yield of MeX from CH4 activation catalysts from 12% to 90%
through the use of “capping arene” ligands. Four (FP) RhIII (Me)(TFA) 2 {FP=“capping arene” …
through the use of “capping arene” ligands. Four (FP) RhIII (Me)(TFA) 2 {FP=“capping arene” …
Highly Efficient and Linear-Selective Hydroformylation of Allyl Acetate Under Mild Conditions Regulated by Additives
M Mei, J Zhao, H Fang, Z Sun, W Xue, H Fu, R Li… - Catalysis Letters, 2024 - Springer
Butanediol, an important chemical raw material, especially as the monomer of engineering
plastic polyethylene terephthalate (PBT), plays a pivotal role in contemporary chemicals. A …
plastic polyethylene terephthalate (PBT), plays a pivotal role in contemporary chemicals. A …
[PDF][PDF] Organometall-Pincer-Komplexe: Reaktionen mit Protonen und Wasserstoff
NR Wiedmaier - 2023 - tobias-lib.ub.uni-tuebingen.de
Die wiederholte Protonierung carbonyl-basierter Eisen-und Ruthenium-Pincer-Komplexe
mit einer Supersäure resultiert in der stufenweisen Hydrierung des ungesättigten Liganden …
mit einer Supersäure resultiert in der stufenweisen Hydrierung des ungesättigten Liganden …