Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics

SQ Su, SQ Wu, S Kanegawa, K Yamamoto… - Chemical Science, 2023 - pubs.rsc.org
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …

Modern history of organic conductors: An overview

T Naito - Crystals, 2021 - mdpi.com
This short review article provides the reader with a summary of the history of organic
conductors. To retain a neutral and objective point of view regarding the history …

Small-molecule ambipolar transistors

T Higashino, T Mori - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Ambipolar transistor properties have been observed in various small-molecule materials.
Since a small energy gap is necessary, many types of molecular designs including extended …

Highly stable and isomorphic donor–acceptor stacking in a family of n-type organic semiconductors of BTBT–TCNQ derivatives

S Matsuoka, K Ogawa, R Ono, K Nikaido… - Journal of Materials …, 2022 - pubs.rsc.org
Herein, we present the common structural features of a family of semiconducting molecular
donor–acceptor (DA) compounds based on alkylated fused-ring thienoacenes. Crystal …

From charge-and spin-ordering to superconductivity in the organic charge-transfer solids

RT Clay, S Mazumdar - Physics Reports, 2019 - Elsevier
We review recent progress in understanding the different spatial broken symmetries that
occur in the normal states of the family of charge-transfer solids (CTS) that exhibit …

Impact of C–H···X (X = F, N) and π–π Interactions on Tuning the Degree of Charge Transfer in F6TNAP-Based Organic Binary Compound Single Crystals

P Hu, S Wang, A Chaturvedi, F Wei, X Zhu… - Crystal Growth & …, 2018 - ACS Publications
Single crystals of four new charge transfer compounds, triphenylene (TP)-1, 3, 4, 5, 7, 8-
hexafluorotetracyanonaphthoquinodimethane (F6TNAP), pyrene-F6TNAP, phenanthrene …

The competitive role of C–H⋯ X (X= F, O) and π–π interactions in contributing to the degree of charge transfer in organic cocrystals: a case study of heteroatom-free …

J Gao, J Guo, Y Chen, S Deng, Q Lu, Y Ren, X Wang… - …, 2022 - pubs.rsc.org
Weak intermolecular interactions, such as π–π interactions, hydrogen bonds, halogen
bonds and charge transfer interactions, are important for tuning the physical properties of …

The stoichiometry of TCNQ-based organic charge-transfer cocrystals

J Gao, H Zhai, P Hu, H Jiang - Crystals, 2020 - mdpi.com
Organic charge-transfer cocrystals (CTCs) have attracted significant research attention due
to their wide range of potential applications in organic optoelectronic devices, organic …

Thermochromism of rapid responses to temperature changes versus mechanochromism in a Ni-dithiolene complex salt

L Xu, YM Wang, ZH Feng, Y Qian, Y Gao, ZF Tian… - Dalton …, 2023 - pubs.rsc.org
A thermochromic or mechanochromic material can switch between at least two stable states
in response to changes in temperature or static pressure/strain. In this study, we investigated …

Temperature-induced neutral-to-ionic phase transition of the charge-transfer crystal tetrathiafulvalene-fluoranil

E Ferrari, F Mezzadri, M Masino - Physical Review B, 2022 - APS
The temperature induced neutral to ionic phase transition (TI-NIT) is a rare phenomenon
occurring in mixed stack charge transfer (CT) crystals made up of alternating π-electron …