The many flavours of mechanochemistry and its plausible conceptual underpinnings

RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …

Advances in quantum mechanochemistry: electronic structure methods and force analysis

T Stauch, A Dreuw - Chemical Reviews, 2016 - ACS Publications
In quantum mechanochemistry, quantum chemical methods are used to describe molecules
under the influence of an external force. The calculation of geometries, energies, transition …

Mechanical gating of a mechanochemical reaction cascade

J Wang, TB Kouznetsova, R Boulatov… - Nature communications, 2016 - nature.com
Covalent polymer mechanochemistry offers promising opportunities for the control and
engineering of reactivity. To date, covalent mechanochemistry has largely been limited to …

Spirolactam and ESIPT in a Double-Network Elastomer: Multicolor Mechanochromism and Dual-Ratiometric Strain Sensing in Low and High Tensile Stress

H Hu, X Cheng, Y Wu, M Chen, Z Ma, Q Yang… - …, 2024 - ACS Publications
Monitoring strain/stress in the bulk polymer material by mechanochromic mechanophores
(MMs) with multimodal analyses can provide valuable information under loading. Herein …

Mechanochemical degradation of denpols: synthesis and ultrasound-induced chain scission of polyphenylene-based dendronized polymers

GI Peterson, KT Bang, TL Choi - Journal of the American Chemical …, 2018 - ACS Publications
New polyphenylene-based dendronized polymers (denpols), exhibiting extended and rigid
conformations, were prepared using ring-opening metathesis polymerization (ROMP). Their …

Hierarchically Structured Deformation‐Sensing Mechanochromic Pigments

JM Clough, C Kilchoer, BD Wilts, C Weder - Advanced Science, 2023 - Wiley Online Library
Mechanochromic materials alter their color in response to mechanical force and are useful
for both fundamental studies and practical applications. Several approaches are used to …

[HTML][HTML] From responsiveness in biological matter to functional materials: Analogies and inspiration towards the systematic design and synthesis of new smart …

MP Cosma, R Brighenti - Applied Materials Today, 2023 - Elsevier
Living organisms and, in general, bio-materials respond to external stimuli exhibiting
specific functionalities (such as shape-morphing, color change, tissue growth and …

Mechanochemical transformations of polysaccharides: A systematic review

TA Akopova, TN Popyrina, TS Demina - International Journal of …, 2022 - mdpi.com
Taking into consideration the items of the Preferred Reporting Items for Systematic Reviews
and Meta-Analyses (PRISMA), this study reviews application of mechanochemical …

Reorganizable and stimuli-responsive polymers based on dynamic carbon–carbon linkages in diarylbibenzofuranones

K Imato, H Otsuka - Polymer, 2018 - Elsevier
The incorporation of dynamic bonds into polymer structures has endowed polymers with
structurally reorganizable properties and stimuli-responsiveness. Their macroscopic …

Mechanical activation of platinum–acetylide complex for olefin hydrosilylation

K Wei, Z Gao, H Liu, X Wu, F Wang, H Xu - ACS Macro Letters, 2017 - ACS Publications
Harnessing mechanical forces to activate latent catalysts has emerged as a novel approach
to control the catalytic reactions in organic syntheses and polymerization processes …