The many flavours of mechanochemistry and its plausible conceptual underpinnings
RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
Advances in quantum mechanochemistry: electronic structure methods and force analysis
In quantum mechanochemistry, quantum chemical methods are used to describe molecules
under the influence of an external force. The calculation of geometries, energies, transition …
under the influence of an external force. The calculation of geometries, energies, transition …
Mechanical gating of a mechanochemical reaction cascade
J Wang, TB Kouznetsova, R Boulatov… - Nature communications, 2016 - nature.com
Covalent polymer mechanochemistry offers promising opportunities for the control and
engineering of reactivity. To date, covalent mechanochemistry has largely been limited to …
engineering of reactivity. To date, covalent mechanochemistry has largely been limited to …
Spirolactam and ESIPT in a Double-Network Elastomer: Multicolor Mechanochromism and Dual-Ratiometric Strain Sensing in Low and High Tensile Stress
Monitoring strain/stress in the bulk polymer material by mechanochromic mechanophores
(MMs) with multimodal analyses can provide valuable information under loading. Herein …
(MMs) with multimodal analyses can provide valuable information under loading. Herein …
Mechanochemical degradation of denpols: synthesis and ultrasound-induced chain scission of polyphenylene-based dendronized polymers
New polyphenylene-based dendronized polymers (denpols), exhibiting extended and rigid
conformations, were prepared using ring-opening metathesis polymerization (ROMP). Their …
conformations, were prepared using ring-opening metathesis polymerization (ROMP). Their …
Hierarchically Structured Deformation‐Sensing Mechanochromic Pigments
Mechanochromic materials alter their color in response to mechanical force and are useful
for both fundamental studies and practical applications. Several approaches are used to …
for both fundamental studies and practical applications. Several approaches are used to …
[HTML][HTML] From responsiveness in biological matter to functional materials: Analogies and inspiration towards the systematic design and synthesis of new smart …
MP Cosma, R Brighenti - Applied Materials Today, 2023 - Elsevier
Living organisms and, in general, bio-materials respond to external stimuli exhibiting
specific functionalities (such as shape-morphing, color change, tissue growth and …
specific functionalities (such as shape-morphing, color change, tissue growth and …
Mechanochemical transformations of polysaccharides: A systematic review
Taking into consideration the items of the Preferred Reporting Items for Systematic Reviews
and Meta-Analyses (PRISMA), this study reviews application of mechanochemical …
and Meta-Analyses (PRISMA), this study reviews application of mechanochemical …
Reorganizable and stimuli-responsive polymers based on dynamic carbon–carbon linkages in diarylbibenzofuranones
K Imato, H Otsuka - Polymer, 2018 - Elsevier
The incorporation of dynamic bonds into polymer structures has endowed polymers with
structurally reorganizable properties and stimuli-responsiveness. Their macroscopic …
structurally reorganizable properties and stimuli-responsiveness. Their macroscopic …
Mechanical activation of platinum–acetylide complex for olefin hydrosilylation
K Wei, Z Gao, H Liu, X Wu, F Wang, H Xu - ACS Macro Letters, 2017 - ACS Publications
Harnessing mechanical forces to activate latent catalysts has emerged as a novel approach
to control the catalytic reactions in organic syntheses and polymerization processes …
to control the catalytic reactions in organic syntheses and polymerization processes …