Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

In this era of portability and rapid technological advances, polymers are more than ever
under pressure to be cheap and offer tailored property profiles. Often, the key lies in …

Block copolymers consist of two or more chemically distinct polymers that are covalently
bound. These materials self-assemble into fascinating mesostructures with features on the …

The preparation of hybrid organic/inorganic nanocomposites comprised of well-defined
polymers was reviewed. In particular, synthetic methods using controlled/“living” radical …

This review summarizes recent work on the polymer-assisted fabrication of well-defined
inorganic and organic nanoparticles with controlled shape, size, and functional properties …

Controlled/living radical polymerizations carried out in the presence of water have been
examined. These aqueous systems include both the homogeneous solutions and the …

Nowadays, controlled (“living”) radical polymerization (C (L) RP) is rapidly expanding as
assessed by a large number of publications, reviews, and patents on this topic. 1-22 This …