Azetidines are prominent structural scaffolds in bioactive molecules, medicinal chemistry,
and ligand design for transition metals. However, state-of-the-art methods cannot be applied …

Oxidative MHAT hydrofunctionalization of alkenes provides a mild cobalt-catalyzed route to
forming C–N and C–O bonds. Here, we characterize relevant salen-supported cobalt …

Catalytic asymmetric hydroamination of alkenes with Lewis basic amines is of great interest
but remains a challenge in synthetic chemistry. Here, we developed a Co‐catalyzed …

The first-row transition-metal-catalyzed hydrogen atom transfer reaction has emerged as a
practical synthetic platform for alkene hydrofunctionalization with high chemo-and …

Four-membered heterocycles are highly sought after in modern drug discovery as they
provide beneficial properties to the target molecules. Despite tremendous efforts by the …

Tricomponent cobalt (salen)-catalyzed carbofunctionalization of unsaturated substrates by
radical–polar crossover has the potential to streamline access to broad classes of …

Remote hydrofunctionalizations of alkenes incorporate functional groups distal to existing
carbon–carbon double bonds. While remote carbonylations are well-known, remote …

A cobalt‐catalyzed intramolecular Markovnikov hydroalkoxycarbonylation and
hydroaminocarbonylation of unactivated alkenes has been developed, enabling highly …

In metal hydride-catalyzed alkene hydrofunctionalization reactions via hydrogen atom
transfer, simple carbonyl groups have been well-recognized as good somophiles at the …

The cycloisomerization of β-, γ-, and δ-unsaturated N-acyl sulfonamides to N-sulfonyl
lactams and imidates is reported. This transformation is effected in the presence of a CoIII …