Efficient Narrowband Circularly Polarized Light Emitters Based on 1, 4‐B, N‐embedded Rigid Donor–Acceptor Helicenes

F Zhang, F Rauch, A Swain, TB Marder… - Angewandte …, 2023 - Wiley Online Library
Narrow‐band emission is essential for applicable circularly polarized luminescence (CPL)
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …

Pyrene-fused [7] helicenes connected via hexagonal and heptagonal rings: Stereospecific synthesis and chiroptical properties

AK Swain, K Radacki, H Braunschweig… - The Journal of organic …, 2022 - ACS Publications
In this manuscript, we portrayed a stereospecific synthesis of C 2-and C 1-symmetric pyrene-
fused [7] helicene compounds 1 and 2, respectively. Compounds 1 and 2 were synthesized …

A Deep‐Red Emissive Sulfur‐Doped Double [7] Helicene Photosensitizer: Synthesis, Structure and Chiral Optical Properties

WW Yang, ZH Ren, J Feng, ZB Lv, X Cheng… - Angewandte …, 2024 - Wiley Online Library
Doping of polycyclic conjugated hydrocarbons (PCHs) with sulfur atoms is becoming more
and more important as a means of creating unique functional materials. Recently, thiophene …

Helicene‐type β‐isoindigo‐based boron‐dipyrromethene analogs with strong near‐infrared chiroptical activity

Z Chen, Z Ni, XY Chen, Y Xu, C Yu, SS Wang… - …, 2024 - Wiley Online Library
Near‐infrared (NIR) chiroptical response has been less explored because it is challenging
to achieve both chirality and NIR absorption/emission. Herein, we describe the design of …

Helicity modulation in nir‐absorbing porphyrin‐ryleneimides

SA Balahoju, YK Maurya… - Angewandte Chemie …, 2022 - Wiley Online Library
Peripheral substitution of a π‐extended porphyrin with bulky groups produces a curved
chromophore with four helical stereogenic units. The curvature and stereochemistry of such …

Axially Chiral Nonbenzenoid Nanographene with Second Harmonic Generation Property

L Qin, J Xie, B Wu, H Hong, S Yang, Z Ma… - Journal of the …, 2024 - ACS Publications
Chiral nanographenes (NGs) have garnered significant interest as optoelectronic materials
in recent years. While helically chiral NGs have been extensively studied, axially chiral NGs …

Pyrene bridged double [7] helicene embedded with a heptagonal ring

A Swain, P Ravat - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
To utilize [n] helicene-embedded polycyclic aromatic hydrocarbons in the development of
circularly polarized materials high luminescence quantum yield and dissymmetric factors are …

Preferential molecular recognition of heterochiral guests within a cyclophane receptor

M Weh, K Shoyama, F Würthner - Nature Communications, 2023 - nature.com
The discrimination of enantiomers by natural receptors is a well-established phenomenon.
In contrast the number of synthetic receptors with the capability for enantioselective …

A Dualistic Arrangement of a Chiral [1] Rotaxane Based on the Assembly of Two Rings and Two Rods

R Katoono, T Tanioka - The Journal of Organic Chemistry, 2023 - ACS Publications
We demonstrate the synthesis and chiroptical properties of doubled molecules of a chiral [1]
rotaxane, based on the assembly of an achiral ring of a phenylacetylene macrocycle (6PAM) …

A Strategy for Polar Crystals with Dipolar Heterohelicenes

S Hiroto, M Wakita, M Chujo - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Polar crystals have attracted interest for the applications to polar materials with piezo‐and
pyroelectricity, and second harmonic generation. Despite their potential utility for flexible …