Efficient Narrowband Circularly Polarized Light Emitters Based on 1, 4‐B, N‐embedded Rigid Donor–Acceptor Helicenes
Narrow‐band emission is essential for applicable circularly polarized luminescence (CPL)
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
Pyrene-fused [7] helicenes connected via hexagonal and heptagonal rings: Stereospecific synthesis and chiroptical properties
AK Swain, K Radacki, H Braunschweig… - The Journal of organic …, 2022 - ACS Publications
In this manuscript, we portrayed a stereospecific synthesis of C 2-and C 1-symmetric pyrene-
fused [7] helicene compounds 1 and 2, respectively. Compounds 1 and 2 were synthesized …
fused [7] helicene compounds 1 and 2, respectively. Compounds 1 and 2 were synthesized …
A Deep‐Red Emissive Sulfur‐Doped Double [7] Helicene Photosensitizer: Synthesis, Structure and Chiral Optical Properties
WW Yang, ZH Ren, J Feng, ZB Lv, X Cheng… - Angewandte …, 2024 - Wiley Online Library
Doping of polycyclic conjugated hydrocarbons (PCHs) with sulfur atoms is becoming more
and more important as a means of creating unique functional materials. Recently, thiophene …
and more important as a means of creating unique functional materials. Recently, thiophene …
Helicene‐type β‐isoindigo‐based boron‐dipyrromethene analogs with strong near‐infrared chiroptical activity
Z Chen, Z Ni, XY Chen, Y Xu, C Yu, SS Wang… - …, 2024 - Wiley Online Library
Near‐infrared (NIR) chiroptical response has been less explored because it is challenging
to achieve both chirality and NIR absorption/emission. Herein, we describe the design of …
to achieve both chirality and NIR absorption/emission. Herein, we describe the design of …
Helicity modulation in nir‐absorbing porphyrin‐ryleneimides
SA Balahoju, YK Maurya… - Angewandte Chemie …, 2022 - Wiley Online Library
Peripheral substitution of a π‐extended porphyrin with bulky groups produces a curved
chromophore with four helical stereogenic units. The curvature and stereochemistry of such …
chromophore with four helical stereogenic units. The curvature and stereochemistry of such …
Axially Chiral Nonbenzenoid Nanographene with Second Harmonic Generation Property
L Qin, J Xie, B Wu, H Hong, S Yang, Z Ma… - Journal of the …, 2024 - ACS Publications
Chiral nanographenes (NGs) have garnered significant interest as optoelectronic materials
in recent years. While helically chiral NGs have been extensively studied, axially chiral NGs …
in recent years. While helically chiral NGs have been extensively studied, axially chiral NGs …
Pyrene bridged double [7] helicene embedded with a heptagonal ring
A Swain, P Ravat - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
To utilize [n] helicene-embedded polycyclic aromatic hydrocarbons in the development of
circularly polarized materials high luminescence quantum yield and dissymmetric factors are …
circularly polarized materials high luminescence quantum yield and dissymmetric factors are …
Preferential molecular recognition of heterochiral guests within a cyclophane receptor
M Weh, K Shoyama, F Würthner - Nature Communications, 2023 - nature.com
The discrimination of enantiomers by natural receptors is a well-established phenomenon.
In contrast the number of synthetic receptors with the capability for enantioselective …
In contrast the number of synthetic receptors with the capability for enantioselective …
A Dualistic Arrangement of a Chiral [1] Rotaxane Based on the Assembly of Two Rings and Two Rods
R Katoono, T Tanioka - The Journal of Organic Chemistry, 2023 - ACS Publications
We demonstrate the synthesis and chiroptical properties of doubled molecules of a chiral [1]
rotaxane, based on the assembly of an achiral ring of a phenylacetylene macrocycle (6PAM) …
rotaxane, based on the assembly of an achiral ring of a phenylacetylene macrocycle (6PAM) …
A Strategy for Polar Crystals with Dipolar Heterohelicenes
S Hiroto, M Wakita, M Chujo - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Polar crystals have attracted interest for the applications to polar materials with piezo‐and
pyroelectricity, and second harmonic generation. Despite their potential utility for flexible …
pyroelectricity, and second harmonic generation. Despite their potential utility for flexible …