Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

A catalytic approach of synthesizing the cis-selective saturated carbo-and heterocyclic
germanium compounds (3D framework) is reported via the hydrogenation of readily …

We report a site-selective ipso-nitration of aryl germanes in the presence of boronic esters,
silanes, halogens, and additional functionalities. The protocol is characterized by …

Organo-silanes, germanes, and stannanes are considered to be conducive to the
development of cross-coupling reactions because they are stable, nontoxic, and easy to …

A direct C (sp)–H germylation of terminal alkynes with triethyl germanium hydride is
reported. The method is operationally simple and makes use of B (C6F5) 3 catalysis in …

The development of novel strategies for the efficient incorporation of germanium into
widespread molecular structures, especially for the synthesis of potentially bioactive …

While the modular construction of molecules from suitable building blocks is a powerful
means to more rapidly generate a diversity of molecules than through customized …

Herein, a novel strategy is presented for the photoinduced decarboxylative and
dehydrogenative cross-coupling of a wide range of α-fluoroacrylic acids with …

The radio‐iodination of arenes is investigated from organosilane and organogermane
precursors using ipso‐electrophilic halogenation (IEH). Discovery of a mild base mediated …

Pd-catalyzed cascade hydroarylation and C–H germylation of nonterminal alkenes and aryl
iodides enabled by hydroxyl assistance have been developed. The key step in this C–H …