Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

pH–rate profiles for aqueous–organic protodeboronation of 18 boronic acids, many widely
viewed as unstable, have been studied by NMR and DFT. Rates were pH-dependent, and …

Despite the widespread application of Suzuki-Miyaura cross-coupling to forge carbon-
carbon bonds, the structure of the reactive intermediates underlying the key transmetalation …

Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Abstract The Suzuki–Miyaura coupling is one of the few transition‐metal‐catalyzed C C
bond‐forming reactions that have been used in applications ranging from discovery …

The Suzuki–Miyaura cross-coupling reaction has emerged as one of the most powerful
methods for the construction of carbon–carbon bonds. Though most widely utilized for the …

The development of an enantioselective catalytic Suzuki–Miyaura reaction that applies to
meso 1, 2-diborylcycloalkanes is described. This reaction provides a modular route to …

The use of water in organic synthesis draws attention to its green chemistry features and its
unique ability to unveil unconventional reactivities. Herein, literature about the use of water …