The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Here we report a nonenzymatic glycosylation reaction that builds axial S-glycosidic bonds
under biorelevant conditions. This strategy is enabled by the design and use of allyl glycosyl …

We herein report a method that enables the generation of glycosyl radicals under highly
acidic conditions. Key to the success is the design and use of glycosyl sulfinates as radical …

The Brook rearrangement has already become established as one of the most important
molecular rearrangements in synthetic chemistry and has been applied in the generation of …

An efficient and stereoretentive copper-catalyzed cross-coupling of glycosyl thiosulfonate
and boronic acid for the construction of thioglycosides is described. The good functional …

C-Glycosyl peptides/proteins are metabolically stable mimics of the native
glycopeptides/proteins bearing O/N-glycosidic linkages, and are thus of great therapeutical …

N-Glycosylated heterocycles play important roles in biological systems and drug
development. The synthesis of these compounds heavily relies on ionic N-glycosylation …

Herein, we describe a novel methodology for the regio-and stereoselective convergent
synthesis of 2-amino-2-deoxy-dithioglycosides via one-pot relay glycosylation of 3-O-acetyl …

Here we report a simple and general method to achieve fully unprotected, stereoselective
glycosylation of carboxylic acids, employing bench‐stable allyl glycosyl sulfones as donors …