Spin crossover in discrete polynuclear iron (II) complexes

RW Hogue, S Singh, S Brooker - Chemical Society Reviews, 2018 - pubs.rsc.org
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …

[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Reversible CO scavenging via adsorbate-dependent spin state transitions in an iron (II)–triazolate metal–organic framework

DA Reed, DJ Xiao, MI Gonzalez… - Journal of the …, 2016 - ACS Publications
A new metal–organic framework, Fe-BTTri (Fe3 [(Fe4Cl) 3 (BTTri) 8] 2· 18CH3OH, H3BTTri=
1, 3, 5-tris (1 H-1, 2, 3-triazol-5-yl) benzene)), is found to be highly selective in the adsorption …

Spin crossover in iron (II) complexes of 3, 4, 5-tri-substituted-1, 2, 4-triazole (Rdpt), 3, 5-di-substituted-1, 2, 4-triazolate (dpt−), and related ligands

HLC Feltham, AS Barltrop, S Brooker - Coordination Chemistry Reviews, 2017 - Elsevier
A general introduction to spin crossover involving iron (II) is provided. Then the 26 examples
of 3, 4, 5-tri-substituted-1, 2, 4-triazole (mostly Rdpt and Rppt) ligands and the 11 examples …

Remarkable scan rate dependence for a highly constrained dinuclear iron (II) spin crossover complex with a wide thermal hysteresis loop

R Kulmaczewski, J Olguín, JA Kitchen… - Journal of the …, 2014 - ACS Publications
The abrupt [HS-HS]↔ localized [HS-LS] spin crossovers of a new triazole-based diiron (II)
complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (Δ …

Electronic control of spin-crossover properties in four-coordinate bis (formazanate) iron (II) complexes

F Milocco, F De Vries, IMA Bartels… - Journal of the …, 2020 - ACS Publications
The transition between spin states in d-block metal complexes has important ramifications
for their structure and reactivity, with applications ranging from information storage materials …

Oxo-and hydroxo-bridged diiron (III) porphyrin dimers: Inorganic and bio-inorganic perspectives and effects of intermacrocyclic interactions

T Guchhait, S Sasmal, FST Khan, SP Rath - Coordination Chemistry …, 2017 - Elsevier
Oxo-and hydroxo-bridged diiron active centers are common structural motifs found in a
variety of proteins in biology. The highly versatile oxo/hydroxo-bridged dimetallic centers …

Solvent Effects on the Structural and Magnetic Properties of FeIII Spin-Crossover Complexes

U Habarakada, T Boonprab, P Harding… - Crystal Growth & …, 2022 - ACS Publications
Molecular devices based on spin-crossover (SCO) compounds are important targets for
molecular electronics. In this study, six air-stable FeIII complexes have been prepared:[Fe …

Lattice Effects on the Spin‐Crossover Profile of a Mononuclear Manganese (III) Cation

K Pandurangan, B Gildea, C Murray… - … A European Journal, 2012 - Wiley Online Library
Six solvated salts of a mononuclear manganese (III) complex with a chelating hexadentate
Schiff base ligand are reported. One member of the series,[MnL] PF6. 0.5 CH3OH (1), shows …

Spin Crossover in Dinuclear N4S2 Iron(II) Thioether–Triazole Complexes: Access to [HS-HS], [HS-LS], and [LS-LS] States

RW Hogue, HLC Feltham, RG Miller… - Inorganic …, 2016 - ACS Publications
Access to a new family of thioether-linked PSRT ligands, 4-substituted-3, 5-bis {[(2-
pyridylmethyl) sulfanyl] methyl}-4 H-1, 2, 4-triazoles (analogues of the previously studied …