Well-defined phosphine-free manganese (II)-complex-catalyzed synthesis of quinolines, pyrroles, and pyridines
Herein, we report a simple, phosphine-free, and inexpensive catalytic system based on a
manganese (II) complex for synthesizing different important N-heterocycles such as …
manganese (II) complex for synthesizing different important N-heterocycles such as …
Single-Molecular Mn(I)-Complex-Catalyzed Tandem Double Dehydrogenation Cross-Coupling of (Amino)Alcohols under Solventless Conditions with the Liberation of H2 and H …
G Sivakumar, M Subaramanian… - … Sustainable Chemistry & …, 2022 - ACS Publications
Sustainable chemical production requires fundamentally new types of catalysts and catalytic
technologies. The development of coherent and robust catalytic systems based on earth …
technologies. The development of coherent and robust catalytic systems based on earth …
Well‐Defined Ni− SNS Complex Catalysed Borrowing Hydrogenative α‐Alkylation of Ketones and Dehydrogenative Synthesis of Quinolines
Abstract The “borrowing hydrogen”(BH) method for C‐alkylation reactions using alcohol as
alkylating agents is an important synthetic transformation. In this respect, designing cheap …
alkylating agents is an important synthetic transformation. In this respect, designing cheap …
A strategic approach for Csp 3–H functionalization of 9 H-fluorene: an acceptorless dehydrogenation and borrowing hydrogen approach
Herein, we described the selective synthesis of both alkylated and alkenylated fluorenes
using a single SNS ligand derived nickel complex. The protocol was employed for a wide …
using a single SNS ligand derived nickel complex. The protocol was employed for a wide …
3d Transition Metal Complexes as Homogeneous Catalysts in N-Alkylation Reactions Using Alcohols: A Recent Update
J Mahato, R Das, TK Saha - Tetrahedron, 2024 - Elsevier
The development of cheap, earth-abundant 3d transition metal catalysts in N-alkylation
reactions of N-nucleophiles utilizing greener reagents alcohols via borrowing hydrogen …
reactions of N-nucleophiles utilizing greener reagents alcohols via borrowing hydrogen …
Chemoselective α‐Alkylation of Nitriles with Primary Alcohols by Manganese(I)‐Catalysis
K Bera, A Mukherjee - Chemistry–An Asian Journal, 2023 - Wiley Online Library
A sustainable and easy‐to‐use protocol for the alkylation of aryl nitriles with the earth‐
abundant manganese (I) catalyst is presented. The alkylation reaction employs readily …
abundant manganese (I) catalyst is presented. The alkylation reaction employs readily …
Arene Binuclear Ru (II)-Promoted Sustainable Synthesis of Substituted Pyrazoles from Alcohols via Acceptorless Dehydrogenative Annulation
T Veerappan, R Rengan - Organic Letters, 2023 - ACS Publications
We report a selective and sustainable synthesis of substituted pyrazoles via an eco-friendly
acceptorless dehydrogenative annulation (ADA) of greener alcohols, malononitrile, and …
acceptorless dehydrogenative annulation (ADA) of greener alcohols, malononitrile, and …
N-Heterocyclic Carbene-Supported Nickel-Catalyzed Selective (Un) Symmetrical N-Alkylation of Aromatic Diamines with Alcohols
The “borrowing hydrogen”(BH) approach for the N-alkylation of phenylenediamines using
alcohols as coupling partners is highly challenging due to the selectivity issue of the …
alcohols as coupling partners is highly challenging due to the selectivity issue of the …
Direct synthesis of benzimidazoles by Pd (II) N^ N^ S-pincer type complexes via acceptorless dehydrogenative coupling of alcohols with diamines
P Anandaraj, R Ramesh, JG Malecki - Journal of Organometallic Chemistry, 2023 - Elsevier
A sustainable synthetic method for the construction of substituted benzimidazoles via
acceptorless dehydrogenative coupling of primary alcohols by palladium catalysts is …
acceptorless dehydrogenative coupling of primary alcohols by palladium catalysts is …
Unveiling the Potential of SNS-Ni Complex for Establishing C–N Bonds: An Approach toward Chemoselectivity
Recent research has focused a lot on using the borrowing hydrogen (BH) approach to react
amines with alcohols to convert a C–O bond into a C–N bond. However, the notion of …
amines with alcohols to convert a C–O bond into a C–N bond. However, the notion of …