For almost 40 years, difluoromethylene phosphonates have proven to be versatile molecular
tools in biochemical studies owing to their close resemblance to naturally occurring …

The first visible‐light‐promoted dearomative fluoroalkylation of β‐naphthols was realized
without the assistance of any transition‐metal catalysts or external photosensitizers …

Among the realm of visible light photocatalytic transformations, late-stage
difluoromethylation reactions (introduction of difluoromethyl groups in the last stages of …

There have been significant developments in the area of perfluoroalkyl group transfer using
silicon reagents, specifically in nucleophilic trifluoromethylation. The mild and versatile …

A new application of trifluoromethylating reagent, methyl fluorosulfonyldifluoroacetate
(FO2SCF2CO2Me, Chen's reagent), as the carbomethoxydifluoromethylating reagent under …

A visible-light-mediated de-aminative alkylation of N-arylamines has been developed,
providing direct access to α-amino C–H functionalization from readily available Katritzky …

A copper‐catalyzed reaction of easily accessible α, α, α‐trifluoromethylketones with various
aldehydes affords difluoro‐methylene compounds in the presence of diboron and NaOtBu …

The difluoromethyl phosphonate motif plays a crucial role in the development of bioactive
molecules as it is considered as a phosphate bioisoster. Since 2010, a renewal of interest to …

We have reported herein a catalyst-free 1, 3-dipolar cycloaddition of C, N-cyclic azomethine
imines and 3-nitroindoles by which a series of five-ring-fused tetrahydroisoquinolines …

The double-oxidative dehydrogenative (DOD) cyclization represents one of the most
straightforward and atom-economical methods for cyclic structure formation. A Cu …