The discovery of the Claisen rearrangement almost a century ago1 offered a potentially
useful synthetic tool to the organic chemist. Over the decades this usefulness has been …

Since its discovery in 1912, 1 the Claisen rearrangement has become one of the most
widely used synthetic tools for the organic chemist. For synthetic purposes, the Claisen …

The ZnCl2-catalyzed three-component synthesis of pyrano [3, 2-c] quinolin-5 (6H)-ones from
the domino reactions of 4-hydroxy-1-methylquinolin-2 (1H)-one, nitroketene N, S …

A series of 1, 3-cyclodiketone-and tetrahydroepoxyisoindole-fused β-enamino dicarbonyl
heterocycles were synthesized via a 1, 4-diazabicyclo [2.2. 2] octane-catalyzed, CH3NO2 …

The combination of experiments and computations reveals unusual features of
stereoselective Rh (I)-catalyzed transformation of propargyl vinyl ethers into (E, Z)-dienals …

1.1 Introduction reaction under kinetic control, for example stoichiometric deprotonation
followed by kinetic protonation. For a long time different thermodynamic stability was only …

The first appearance of the thio-Claisen rearrangement (TCR) in the literature 1 occurred in
1962. The TCR is the sulfur analogue of the simple Claisen rearrangement. 2–6 Classically …

Hitherto unreported 2H-thiopyrano [3, 2-c][1] benzopyran-5-ones 6a–f are synthesized
regioselectively in 79–85% yields by the thio-Claisen rearrangement of 4-propargylthio [1] …

A convenient and effective one‐pot synthetic method for functionalized 1H‐thiopyrano [4, 3‐
c] quinoline scaffold via three‐component cyclization is described. This procedure contains …

The thio-Claisen rearrangement is a general and facile process that is often advantageous
overthe standard Claisen rearrangement. Several asymmetric variants of the thio-Claisen …